About: Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.electrochemsci.org/papers/vol9/91206910.pdf
Description	In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed at different concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01 to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products. In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed at different concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01 to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products. (en)
Title	Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis (en)
skos:prefLabel	Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis (en)
skos:notation	RIV/70883521:28140/14:43871536!RIV15-MSM-28140___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0089)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Beltrán Prieto, Juan Carlos Kolomazník, Karel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Tomáše Bati ve Zlíně / Fakulta aplikované informatiky
http://linked.open...dnocenehoVysledku	14226
http://linked.open...ai/riv/idVysledku	RIV/70883521:28140/14:43871536
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	glycerin, potential sweep, controlled potential, anodic oxidation, platinum electrode (en)
http://linked.open.../riv/klicoveSlovo	controlled potential potential sweep anodic oxidation glycerin platinum electrode
http://linked.open...odStatuVydavatele	RS - Srbská republika
http://linked.open...ontrolniKodProRIV	[1DFA4EF85338]
http://linked.open...i/riv/nazevZdroje	International Journal of Electrochemical Sciences
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	The Centre of Security, Information and Advanced Technologies (CEBIA-Tech)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	2014
http://linked.open...iv/tvurceVysledku	Kolomazník, Karel Slavík, Roman Beltrán Prieto, Juan Carlos
http://linked.open...ain/vavai/riv/wos	000345261900019
issn	1452-3981
number of pages	14 (xsd:int)
http://localhost/t...ganizacniJednotka	28140

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