About: Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://ecst.ecsdl.org/content/63/1/145.abstract
Description	The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by %22applying potential on the working electrode%22 without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell. The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by %22applying potential on the working electrode%22 without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell. (en)
Title	Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode (en)
skos:prefLabel	Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode (en)
skos:notation	RIV/00216305:26620/14:PU112373!RIV15-MSM-26620___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED1.1.00/02.0068)
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Vanýsek, Petr
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoké učení technické v Brně / Středoevropský technologický institut
http://linked.open...dnocenehoVysledku	14124
http://linked.open...ai/riv/idVysledku	RIV/00216305:26620/14:PU112373
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	impedance, 3-electrode cell, potentiostat, experimental artifact, (en)
http://linked.open.../riv/klicoveSlovo	3-electrode cell experimental artifact impedance potentiostat
http://linked.open...ontrolniKodProRIV	[E797965D344B]
http://linked.open...v/mistoKonaniAkce	Brno
http://linked.open...i/riv/mistoVydani	Pennington, NJ
http://linked.open...i/riv/nazevZdroje	15th International Conference on Advanced Batteries, Accumulators and Fuel Cells (ABAF 2014)
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Central european institute of technology
http://linked.open...UplatneniVysledku	2014
http://linked.open...iv/tvurceVysledku	Vanýsek, Petr Pilson, Kate-Leigh Tavassol, Hadi
http://linked.open...vavai/riv/typAkce	WRD - Světová
http://linked.open.../riv/zahajeniAkce	2014-08-24 (xsd:date)
number of pages	11 (xsd:int)
http://bibframe.org/vocab/doi	10.1149/06301.0145ecst
http://purl.org/ne...btex#hasPublisher	The Electrochemical Society
https://schema.org/isbn	978-1-62332-230-4
http://localhost/t...ganizacniJednotka	26620

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