About: Thermodynamically controlled macrocyclization: size and shape selection from dynamic libraries through template effects     Goto   Sponge   NotDistinct   Permalink

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Description
  • using of thermodynamically controlled, fully reversible reactions for the generation of macrocyclic compounds (en)
  • použití termodynamicky řízených, plně reverzních reakcí pro tvorbu makrocyklických sloučenin
Title
  • Thermodynamically controlled macrocyclization: size and shape selection from dynamic libraries through template effects (en)
  • Makrocyklizace za podmínek thermodynamické rovnováhy: výběr velikosti a tvaru z dynamických knihoven vlivem templátového efektu
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  • OC 172
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  • thermodynamically controlled, fully reversible reactions; generation of macrocyclic compounds; macrocyclization (en)
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  • Byly nalezeny podmínky pro řízení makrocyklizací difukčních cyklodextrinových derivátů nesoucích sulfanilové skupiny. Rovnováhu monomer-dimer (duplex) lze řídit jak koncentrací, tak přídavkem templátu, který s daným duplexem tvoří pevný komplex. (cs)
  • Macrocyclization of difunctional cyclodextrin derivatives bearing sulfanil groups can be directed to either intramolecular monomeric or dimeric species (duplexes) via changes of the concentration or by addition of a template. (en)
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  • fully reversible reactions
  • generation of macrocyclic compounds
  • thermodynamically controlled
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