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Description
  • Vapour pressure plays a critically important role in a number of applications ranging from technology to ecology. Thought there is a vast number of compounds with well established vapour pressures, measurements are still needed, especially in the low pressure region (below 1 kPa). Static method is a well established method for vapour pressure measurement. On the other hand, need of very pure and carefully degassed samples makes the method laborious, costly and slow. Methods based on determination of gas-chromatographic retention time are fast and require only a very small amount of the compound. In contrary to most other methods, sample purity is of little concern. Besides these promising features there are some limitations and disadvantages (e.g. activity coefficient problems, accurate data for reference compounds). Combination of the two techniques can solve most of the problems currently encountered. (en)
  • 1) Získat nová přesná experimentální data o tlaku nasycených par v nízkotenzní oblasti pro vybrané skupiny látek, 2) Výrazně zvýšit efektivitu stávajících zařízení pro čištění a odplyňování vzorků, 3) Zásadním způsobem zlepšit metodiku stanovení tlaku nasycených par chromatografickou metodou.
Title
  • Development and application of methology for vapour pressure determination by a combination of static and chromatographic techniques (en)
  • Vývoj a aplikace metodiky pro stanovení tlaku nasycených par kombinací statické a chromatografické metody
skos:notation
  • GA203/09/1327
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  • tlak nasycených par; statická metoda; plynová chromatografie (en)
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  • The project gone according to plan both in terms of expertise and in terms of disbursement of funds. (en)
  • Řešení projektu proběhlo podle plánu jak z hlediska odborného tak i z hlediska čerpání finančních prostředků. (cs)
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  • statická metoda
  • tlak nasycených par
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