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  • This paper presents the application of the tubular detector based on silver solid amalgam (TD-AgSA) for electrochemical determinations of reducible inorganic (Cd2+, Zn2+) and organic (4-nitrophenol) compounds under flow injection analysis conditions. The newly developed TD-AgSA is simple, robust and inexpensive. The limits of detections of Zn2+, Cd2+ and 4-nitrophenol are 1.4106, 7.0107, and 5.0107 mol dm3, respectively (i.e. 0.09, 0.08 and 0.07 ppm). The obtained results proved the long-term stability of the detector (RSD of the determination of Zn2+, Cd2+, and 4-nitrophenol were 0.8, 0.9 and 0.8 % (n=10; cZn=7.7105 mol dm3, cCd=4.5105 mol dm3 and c4-NPh=3.6105 mol dm3), respectively and its applicability for cathodic measurements in aqueous solutions at potentials up to 2 V.
  • This paper presents the application of the tubular detector based on silver solid amalgam (TD-AgSA) for electrochemical determinations of reducible inorganic (Cd2+, Zn2+) and organic (4-nitrophenol) compounds under flow injection analysis conditions. The newly developed TD-AgSA is simple, robust and inexpensive. The limits of detections of Zn2+, Cd2+ and 4-nitrophenol are 1.4106, 7.0107, and 5.0107 mol dm3, respectively (i.e. 0.09, 0.08 and 0.07 ppm). The obtained results proved the long-term stability of the detector (RSD of the determination of Zn2+, Cd2+, and 4-nitrophenol were 0.8, 0.9 and 0.8 % (n=10; cZn=7.7105 mol dm3, cCd=4.5105 mol dm3 and c4-NPh=3.6105 mol dm3), respectively and its applicability for cathodic measurements in aqueous solutions at potentials up to 2 V. (en)
Title
  • Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems
  • Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems (en)
skos:prefLabel
  • Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems
  • Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems (en)
skos:notation
  • RIV/61388955:_____/12:00385013!RIV13-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP206/11/1638), S
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Yosypchuk, Bogdan
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
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  • 175299
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/12:00385013
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  • flow injection analysis; tubular detector; silver solid amalgam (en)
http://linked.open.../riv/klicoveSlovo
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  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [E68F355E7F50]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 24
http://linked.open...iv/tvurceVysledku
  • Barek, J.
  • Yosypchuk, Bogdan
  • Yosypchuk, O.
http://linked.open...ain/vavai/riv/wos
  • 000311910800003
issn
  • 1040-0397
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/elan.201200443
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