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rdf:type
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Description
| - Formation and properties of thiol (HS(CH2)10COOH or HS(CH2)10CH3) monolayers were investigated at stationary electrodes based on silver, copper, bismuth and cadmium solid amalgams covered by a mercury meniscus or by a mercury film (m-AgSAE, MF-AgSAE, m-CuSAE, m-BiAgSAE and m-CdSAE). For comparison, parallel experiments were performed at a classical hanging mercury drop electrode (HMDE). Thiol monolayers were prepared at an optimal deposition potential (e.g., for HS(CH2)10COOH Eac = 350 mV for HMDE and silver amalgam electrodes, Eac = 750 to 800 mV for m-CuSAE and m-BiAgSAE, and Eac = 1050 mV for m-CdSAE) at which the formed layers exhibit high density and stability. It was found that the potential of a reductive desorption peak of a thiol monolayer strongly depends on the metal which forms the amalgam (for HS(CH2)10COOH: Ep = 864 to 859 mV for HMDE and silver amalgam electrodes, Em-BiAgSAE = 1079 mV, Em-CuSAE = 1136 mV and Em-CdSAE = 1248 mV).
- Formation and properties of thiol (HS(CH2)10COOH or HS(CH2)10CH3) monolayers were investigated at stationary electrodes based on silver, copper, bismuth and cadmium solid amalgams covered by a mercury meniscus or by a mercury film (m-AgSAE, MF-AgSAE, m-CuSAE, m-BiAgSAE and m-CdSAE). For comparison, parallel experiments were performed at a classical hanging mercury drop electrode (HMDE). Thiol monolayers were prepared at an optimal deposition potential (e.g., for HS(CH2)10COOH Eac = 350 mV for HMDE and silver amalgam electrodes, Eac = 750 to 800 mV for m-CuSAE and m-BiAgSAE, and Eac = 1050 mV for m-CdSAE) at which the formed layers exhibit high density and stability. It was found that the potential of a reductive desorption peak of a thiol monolayer strongly depends on the metal which forms the amalgam (for HS(CH2)10COOH: Ep = 864 to 859 mV for HMDE and silver amalgam electrodes, Em-BiAgSAE = 1079 mV, Em-CuSAE = 1136 mV and Em-CdSAE = 1248 mV). (en)
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Title
| - Properties of thiolate monolayers formed on different amalgam electrodes
- Properties of thiolate monolayers formed on different amalgam electrodes (en)
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skos:prefLabel
| - Properties of thiolate monolayers formed on different amalgam electrodes
- Properties of thiolate monolayers formed on different amalgam electrodes (en)
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skos:notation
| - RIV/61388955:_____/11:00358449!RIV12-GA0-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GAP206/11/1638), P(IAA400400806), P(LC06063), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/11:00358449
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - thiolate monolayer; reductive desorption; charge effect (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| - Journal of Electroanalytical Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
| |
http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Yosypchuk, Bogdan
- Mareček, Vladimír
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.jelechem.2011.01.017
|