About: Structural phase transitions in SrRh2As2.     Goto   Sponge   NotDistinct   Permalink

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  • SrRh2As2 crystallizes with three polymorphs derived from the tetragonal ThCr2Si2-type structure and exhibits structural phase transitions comparable to those of BaFe2As2, a parent compound of iron-based superconductors. The structure of α-SrRh2As2 is monoclinic and was refined as a twin in the space group P21/c with R1 = 0.0928. β-SrRh2As2 crystallizes with a modulated structure in the (3 + 1)-dimensional superspace group Fmmm(10γ )s00 (a = 1114.4(3) pm, b = 574.4(2) pm, and c = 611.5(2) pm) and an incommensurable modulation vector q = (1,0,0.3311(4)).
  • SrRh2As2 crystallizes with three polymorphs derived from the tetragonal ThCr2Si2-type structure and exhibits structural phase transitions comparable to those of BaFe2As2, a parent compound of iron-based superconductors. The structure of α-SrRh2As2 is monoclinic and was refined as a twin in the space group P21/c with R1 = 0.0928. β-SrRh2As2 crystallizes with a modulated structure in the (3 + 1)-dimensional superspace group Fmmm(10γ )s00 (a = 1114.4(3) pm, b = 574.4(2) pm, and c = 611.5(2) pm) and an incommensurable modulation vector q = (1,0,0.3311(4)). (en)
Title
  • Structural phase transitions in SrRh2As2.
  • Structural phase transitions in SrRh2As2. (en)
skos:prefLabel
  • Structural phase transitions in SrRh2As2.
  • Structural phase transitions in SrRh2As2. (en)
skos:notation
  • RIV/68378271:_____/12:00379204!RIV13-AV0-68378271
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  • 171835
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  • RIV/68378271:_____/12:00379204
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  • phase transitions; twining; modulated crystals (en)
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  • Physical Review. B
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  • 85
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  • Dušek, Michal
  • Petříček, Václav
  • Johrendt, D.
  • Zinth, V.
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  • 000299266900008
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  • 1098-0121
number of pages
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  • 10.1103/PhysRevB.85.014109
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