About: The carbonization of thin polyaniline films

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Polyaniline films on silicon and ceramic supports were prepared in situ during the oxidative polymerization of aniline. The films were heated up to 500°C in an inert nitrogen atmosphere. The changes in molecular structure during the carbonization have been studied by infrared spectroscopy and Raman scattering using 514, 633 and 785 nm laser excitation lines. The transformation from polyaniline salt to the base form has been detected above 100°C. The conversion to nitrogen-containing carbon-like material followed above 200°C. The molecular structure of the films produced during heating to 500°C contains crosslinked phenazine-like and oxidized quinonoid units. The aniline oligomers deposited on the support in the early stages of aniline oxidation are stable during heating as it has been observed by resonance Raman scattering using 785 nm laser excitation line. The water contact angles changed after carbonization, and the films became more hydrophilic as carbonization progressed. Polyaniline films on silicon and ceramic supports were prepared in situ during the oxidative polymerization of aniline. The films were heated up to 500°C in an inert nitrogen atmosphere. The changes in molecular structure during the carbonization have been studied by infrared spectroscopy and Raman scattering using 514, 633 and 785 nm laser excitation lines. The transformation from polyaniline salt to the base form has been detected above 100°C. The conversion to nitrogen-containing carbon-like material followed above 200°C. The molecular structure of the films produced during heating to 500°C contains crosslinked phenazine-like and oxidized quinonoid units. The aniline oligomers deposited on the support in the early stages of aniline oxidation are stable during heating as it has been observed by resonance Raman scattering using 785 nm laser excitation line. The water contact angles changed after carbonization, and the films became more hydrophilic as carbonization progressed. (en)
Title	The carbonization of thin polyaniline films The carbonization of thin polyaniline films (en)
skos:prefLabel	The carbonization of thin polyaniline films The carbonization of thin polyaniline films (en)
skos:notation	RIV/61389013:_____/12:00378731!RIV13-AV0-61389013
http://linked.open...avai/predkladatel	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(GAP205/12/0911), P(IAA100500902), P(IAA400500905), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika	19
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Exnerová, Milena Morávková, Zuzana Stejskal, Jaroslav Trchová, Miroslava
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	125979
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/12:00378731
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	polyaniline; thin films; infrared spectroscopy (en)
http://linked.open.../riv/klicoveSlovo	infrared spectroscopy thin films polyaniline
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[E4C865C61DBF]
http://linked.open...i/riv/nazevZdroje	Thin Solid Films
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Aniline oligomers and their role in the formation of polyaniline nanostructures –spectroscopic analysis Surface-enhanced Raman scattering of conducting polymers Preparation and properties of nanostructures produced by condcuting polymers
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	520
http://linked.open...iv/tvurceVysledku	Exnerová, Milena Morávková, Zuzana Stejskal, Jaroslav Trchová, Miroslava
http://linked.open...ain/vavai/riv/wos	000306104900007
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie
issn	0040-6090
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.tsf.2012.05.067
is http://linked.open...avai/riv/vysledek of	The carbonization of thin polyaniline films

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