About: Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byly pozorovány výrazné oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu, lišící se v parametrech a v reakčních podmínkách od oscilačního chování popsaného dříve pro tuto reakci na Fe-zeolitech. Tyto pozorované pravidelné oscilace v konverzi N2O byly doprovázeny pravidelnými oscilacemi v rychlosti vzniku N2 a O2, a to v suché reakční směsi N2O/He a byly reversibilně zhášeny přídavkem NO/NO2 do směsi. Tyto jevy byly pozorovány v rozsahu teplot 400-450oC pro Fe/Pt-ferrierit, s periodami v rozsahu 0.5-3.5 min. Pro Fe-ferrierit byl teplotní rozsah oscilačního chování posunut k vyšším teplotám (t.j. 450-500oC). Na rozdíl od Fe/Pt-ferrieritu, se perioda oscilací na Fe-ferrieritu prakticky neměnila s teplotou. Tvar oscilací na obou katalyzátorech byl složitý a závisel na reakčních podmínkách. (cs)
  • Well-expressed oscillation of the N2O decomposition over Fe- and Fe/Pt-ferrierite catalysts has been observed, differing both in parameters and conditions from the oscillation behavior described previously for the same reaction over Fe-zeolites. The observed regular oscillation in the N2O conversion was accompanied by changes on N2 and O2 production in a dry N2O/He gas stream and was quenched reversibly after NO/NO2 addition. The results were observed in the temperature region 400-450oC over Fe/Pt-ferrierite, with periods of 0.5-3.5 min. For Fe-ferrierite, the temperature region for the oscillation behavior was sliághtly higher (i.e. 450-500oC). In triking contrast to Fe/Pt-ferrierite, the period of oscillation did not change with temperature over Fe-ferrierite. The patterns of the oscillation over both catalysts were complex and depended on the reaction conditions.
  • Well-expressed oscillation of the N2O decomposition over Fe- and Fe/Pt-ferrierite catalysts has been observed, differing both in parameters and conditions from the oscillation behavior described previously for the same reaction over Fe-zeolites. The observed regular oscillation in the N2O conversion was accompanied by changes on N2 and O2 production in a dry N2O/He gas stream and was quenched reversibly after NO/NO2 addition. The results were observed in the temperature region 400-450oC over Fe/Pt-ferrierite, with periods of 0.5-3.5 min. For Fe-ferrierite, the temperature region for the oscillation behavior was sliághtly higher (i.e. 450-500oC). In triking contrast to Fe/Pt-ferrierite, the period of oscillation did not change with temperature over Fe-ferrierite. The patterns of the oscillation over both catalysts were complex and depended on the reaction conditions. (en)
Title
  • Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition
  • Isothermální oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu (cs)
  • Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition (en)
skos:prefLabel
  • Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition
  • Isothermální oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu (cs)
  • Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition (en)
skos:notation
  • RIV/61388955:_____/06:00040531!RIV07-AV0-61388955
http://linked.open.../vavai/riv/strany
  • 270;277
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP104/02/D124), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 480526
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/06:00040531
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Fe-ferrierite; Fe/Pt-ferrierite; N2O decomposition; oscillation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [015DEAB60414]
http://linked.open...i/riv/nazevZdroje
  • Journal of Catalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 242
http://linked.open...iv/tvurceVysledku
  • Nováková, Jana
  • Sobalík, Zdeněk
  • Kaucký, Dalibor
  • Jíša, Kamil
  • Vondrová, Alena
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9517
number of pages
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