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Description
  • Příklad chemického oscilačního systému je oxidace thiosíranu peroxidem vodíku katalyzovaná ionty mědi (reakce HPTCu). Dynamické chování této reakce se vyznačuje vícenásobnými stacionárními stavy, excitabilitou, a oscilacemi. Oscilační režim byl zkoumán pomocí metody fázového posuvu reprezentované křivkami fázového posuvu (PTC). Všechny chemické oscilátory mohou být setříděny pomocí teorie stechiometrických sítí do několika skupin. Zde řešený problém je otázka, zdali křivky PTC mohou být použity k uvedené klasifikaci. Tyto křivky jsou měřeny a počítány pro model reakce a pro prototypické modely jednotlivých kategorií chemických oscilátorů. Je provedeno srovnání a diskutována kategorizace vedoucí k návrhu zlepšení modelu.. (cs)
  • An example of a chemical oscillatory system is oxidation of thiosulfate by hydrogen peroxide catalyzed by cupric ions (HPTCu reaction). Its dynamic behavior is marked by the occurrence of multiple steady states, excitability and oscillations. We study this reaction by exploring the oscillatory regime with the method of phase response. Results are presented in the form of phase transition curves (PTC). Based on the stoichiometric network analysis, all chemical oscillators can be classified into several categories. The main issue addressed here is whether is it also possible to categorize the HPTCu reaction by using phase transition curves. Phase transition curves are measured experimentally, calculated for a model of HPTCu reaction, and calculated for the prototypes of categories of chemical oscillators. By comparison of experimental PTCs with those for the prototypes, the experimental system is classified and roles of reactants are deduced. Likewise, the model of the HPTCu reaction is compared with pr
  • An example of a chemical oscillatory system is oxidation of thiosulfate by hydrogen peroxide catalyzed by cupric ions (HPTCu reaction). Its dynamic behavior is marked by the occurrence of multiple steady states, excitability and oscillations. We study this reaction by exploring the oscillatory regime with the method of phase response. Results are presented in the form of phase transition curves (PTC). Based on the stoichiometric network analysis, all chemical oscillators can be classified into several categories. The main issue addressed here is whether is it also possible to categorize the HPTCu reaction by using phase transition curves. Phase transition curves are measured experimentally, calculated for a model of HPTCu reaction, and calculated for the prototypes of categories of chemical oscillators. By comparison of experimental PTCs with those for the prototypes, the experimental system is classified and roles of reactants are deduced. Likewise, the model of the HPTCu reaction is compared with pr (en)
Title
  • STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD.
  • STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD. (en)
  • Studium oscilační reakce HPTCu pomocí metody fázové odezvy (cs)
skos:prefLabel
  • STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD.
  • STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD. (en)
  • Studium oscilační reakce HPTCu pomocí metody fázové odezvy (cs)
skos:notation
  • RIV/60461373:22340/05:00014444!RIV06-GA0-22340___
http://linked.open.../vavai/riv/strany
  • 069/1-069/10
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GD104/03/H141), Z(MSM6046137306)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 545286
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/05:00014444
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • pH-oscillation; phase transition curves (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [5958BEB5576B]
http://linked.open...v/mistoKonaniAkce
  • Tatranské Matliare, Slovensko
http://linked.open...i/riv/mistoVydani
  • Bratislava
http://linked.open...i/riv/nazevZdroje
  • Proc. of 32th International Conference of Slovak Society of Chemical Engineering.
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Schreiber, Igor
  • Schreiberová, Lenka
  • Bakeš, Daniel
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Slovenská technická univerzita v Bratislave
https://schema.org/isbn
  • 80-227-2224-3
http://localhost/t...ganizacniJednotka
  • 22340
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