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Description
  • systém Bi-Sr-Mn-O;termodynamické modelování;fázové diagramy (cs)
  • The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective ternary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [ Bi3+1-xSr2+x] [ Mn3+1-x+2? Mn4+x-2?] [O2-1-?/3 V a?/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases.
  • The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective ternary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [ Bi3+1-xSr2+x] [ Mn3+1-x+2? Mn4+x-2?] [O2-1-?/3 V a?/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases. (en)
Title
  • Phase equilibria modelling in Bi-Sr-Mn-O system
  • Phase equilibria modelling in Bi-Sr-Mn-O system (en)
  • Modelování fázových rovnovah v systému Bi-Sr-Mn-O (cs)
skos:prefLabel
  • Phase equilibria modelling in Bi-Sr-Mn-O system
  • Phase equilibria modelling in Bi-Sr-Mn-O system (en)
  • Modelování fázových rovnovah v systému Bi-Sr-Mn-O (cs)
skos:notation
  • RIV/60461373:22310/05:00015121!RIV06-MSM-22310___
http://linked.open...avai/riv/aktivita
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  • Z(MSM 223100002)
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  • 535868
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  • RIV/60461373:22310/05:00015121
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  • Phase equilibria modelling in Bi-Sr-Mn-O system (en)
http://linked.open.../riv/klicoveSlovo
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  • [2914AAF472A5]
http://linked.open...in/vavai/riv/obor
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http://linked.open...UplatneniVysledku
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  • Beneš, Ondřej
  • Leitner, Jindřich
  • Nevřiva, Miloš
  • Sedmidubský, David
  • Strejc, Aleš
http://linked.open...n/vavai/riv/zamer
http://localhost/t...ganizacniJednotka
  • 22310
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