About: Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces

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Description	The formation of extended two-dimensional metal-organic coordination networks (2D-MOCNs) showing high adaptability to surface step edges and structural defects is revealed by scanning tunneling microscopy. Rod-like 4,4'-di-(1,4-buta-1,3-diynyl)-benzoic acid (BDBA) and iron atoms assemble into extended 2D-MOCNs on Au(111) and Ag(100) surfaces. Independent from the chosen substrate and its surface symmetry the MOCN grows continuously over multiple surface terraces through mutual inphase structure adaptation of network domains at step edges as well as on terraces. The adaptability of the MOCNs is mainly ascribed to the high degree of conformational flexibility of the butadiynyl functionality of the ligand. Despite their flexibility, the MOCNs exhibit considerable robustness against annealing at high temperatures. The findings show that mesoscale self-assembled functional architectures with a high degree of substrate error tolerance can be realized with metal coordination networks. The formation of extended two-dimensional metal-organic coordination networks (2D-MOCNs) showing high adaptability to surface step edges and structural defects is revealed by scanning tunneling microscopy. Rod-like 4,4'-di-(1,4-buta-1,3-diynyl)-benzoic acid (BDBA) and iron atoms assemble into extended 2D-MOCNs on Au(111) and Ag(100) surfaces. Independent from the chosen substrate and its surface symmetry the MOCN grows continuously over multiple surface terraces through mutual inphase structure adaptation of network domains at step edges as well as on terraces. The adaptability of the MOCNs is mainly ascribed to the high degree of conformational flexibility of the butadiynyl functionality of the ligand. Despite their flexibility, the MOCNs exhibit considerable robustness against annealing at high temperatures. The findings show that mesoscale self-assembled functional architectures with a high degree of substrate error tolerance can be realized with metal coordination networks. (en)
Title	Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces (en)
skos:prefLabel	Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces (en)
skos:notation	RIV/00216305:26620/12:PU98446!RIV13-MSM-26620___
http://linked.open...avai/predkladatel	Středoevropský technologický institut
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED1.1.00/02.0068)
http://linked.open...iv/cisloPeriodika	14
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Čechal, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoké učení technické v Brně / Středoevropský technologický institut
http://linked.open...dnocenehoVysledku	139001
http://linked.open...ai/riv/idVysledku	RIV/00216305:26620/12:PU98446
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Surfaces, coordination chamistry, UHV, metal-organic structures, STM, adaptability. (en)
http://linked.open.../riv/klicoveSlovo	Surfaces UHV adaptability. coordination chamistry metal-organic structures STM
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[BDCE72C6ED0A]
http://linked.open...i/riv/nazevZdroje	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Central european institute of technology
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	134
http://linked.open...iv/tvurceVysledku	Čechal, Jan Ruben, Mario Kern, Klaus Kley, Charistopher S. Kumagai, Takashi Schramm, Frank Stepanow, Sebastian
http://linked.open...ain/vavai/riv/wos	000302524800005
issn	0002-7863
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	26620
is http://linked.open...avai/riv/vysledek of	Highly Adaptable Two-Dimensional Metal-Organic Coordination Networks on Metal Surfaces

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