About: Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (\|aiso(13C)\| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra. EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (\|aiso(13C)\| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra. (en) EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (\|aiso(13C)\| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra. (cs)
Title	Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands (en) Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands (cs)
skos:prefLabel	Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands (en) Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands (cs)
skos:notation	RIV/00216275:25310/07:00006086!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	508-512
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	45
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Černošek, Zdeněk Vinklárek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	457468
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/07:00006086
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	bent metallocene; pseudohalide complexes; EPR spectroscopy; super-hyperfine coupling; X-ray structure (en)
http://linked.open.../riv/klicoveSlovo	X-ray structure EPR spectroscopy super-hyperfine coupling bent metallocene pseudohalide complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[F52988549B9B]
http://linked.open...i/riv/nazevZdroje	Magnetic Resonance in Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	45
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Vinklárek, Jaromír Černošek, Zdeněk Honzíček, Jan
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0749-1581
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands

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