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Description
| - Byla studována silanizace skleněných makroporézních mikrovláken (3-aminopropyl)triethoxysilanem (APTES) a následující navázání [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilseskvioxanu (E-POSS) na aminové skupiny mikrovláken. XPS spektra ukázala, že mikrovlákna se sorbovanou kyselinou kovalentně naváží o 42 % více APTES a potom o 65 % více E-POSS než mikrovlákna se sorbovaným amoniakem. Modelové výpočty (za předpokladu siliky jako matrice, úplné hydrolýzy ethoxy skupin a vertikální kondenzace APTES) ukázaly, že na povrchu vzniká většinou dvojvrstva APTES. (cs)
- Silanization of macroporous glass microfiber filters with (3-aminopropyl)triethoxysilane (APTES) and subsequent binding of [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane (E-POSS) to the amine-terminated surface of microfibers was studied. It was proved by XPS that microfibers with the adsorbed acid take up higher amounts of covalently attached APTES by 42% and, subsequently, of E-POSS by 65% than microfibers with the adsorbed ammonia. The molecular mechanics model calculations, which were made using silica as a template, have shown that approximately two-layered APTES coating can be built on the model surface if complete hydrolysis of ethoxy groups and vertical condensation of APTES species are assumed.
- Silanization of macroporous glass microfiber filters with (3-aminopropyl)triethoxysilane (APTES) and subsequent binding of [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane (E-POSS) to the amine-terminated surface of microfibers was studied. It was proved by XPS that microfibers with the adsorbed acid take up higher amounts of covalently attached APTES by 42% and, subsequently, of E-POSS by 65% than microfibers with the adsorbed ammonia. The molecular mechanics model calculations, which were made using silica as a template, have shown that approximately two-layered APTES coating can be built on the model surface if complete hydrolysis of ethoxy groups and vertical condensation of APTES species are assumed. (en)
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Title
| - Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay
- Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay (en)
- Vznik povrchové dvojvrstvy (3-aminopropyl)triethoxysilanu-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilsesviioxanu prostřednictvím skleněných mikrovláken s povrchem tvořeným systémem kyselina/zásada (cs)
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skos:prefLabel
| - Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay
- Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay (en)
- Vznik povrchové dvojvrstvy (3-aminopropyl)triethoxysilanu-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilsesviioxanu prostřednictvím skleněných mikrovláken s povrchem tvořeným systémem kyselina/zásada (cs)
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skos:notation
| - RIV/61389013:_____/06:00032080!RIV06-AV0-61389013
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/02/1327), Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/06:00032080
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - silanization; (3-amonipropyl)triethoxysilanes; epoxycyclohexylisobutyl polyhedral oligomeric silsesquioxane (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dybal, Jiří
- Tishchenko, Galina
- Sedláková, Zdeňka
- Bastl, Zdeněk
- Brus, Jiří
- Pekárek, Michal
- Bleha, Miroslav
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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