About: Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byla studována silanizace skleněných makroporézních mikrovláken (3-aminopropyl)triethoxysilanem (APTES) a následující navázání [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilseskvioxanu (E-POSS) na aminové skupiny mikrovláken. XPS spektra ukázala, že mikrovlákna se sorbovanou kyselinou kovalentně naváží o 42 % více APTES a potom o 65 % více E-POSS než mikrovlákna se sorbovaným amoniakem. Modelové výpočty (za předpokladu siliky jako matrice, úplné hydrolýzy ethoxy skupin a vertikální kondenzace APTES) ukázaly, že na povrchu vzniká většinou dvojvrstva APTES. (cs)
  • Silanization of macroporous glass microfiber filters with (3-aminopropyl)triethoxysilane (APTES) and subsequent binding of [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane (E-POSS) to the amine-terminated surface of microfibers was studied. It was proved by XPS that microfibers with the adsorbed acid take up higher amounts of covalently attached APTES by 42% and, subsequently, of E-POSS by 65% than microfibers with the adsorbed ammonia. The molecular mechanics model calculations, which were made using silica as a template, have shown that approximately two-layered APTES coating can be built on the model surface if complete hydrolysis of ethoxy groups and vertical condensation of APTES species are assumed.
  • Silanization of macroporous glass microfiber filters with (3-aminopropyl)triethoxysilane (APTES) and subsequent binding of [2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane (E-POSS) to the amine-terminated surface of microfibers was studied. It was proved by XPS that microfibers with the adsorbed acid take up higher amounts of covalently attached APTES by 42% and, subsequently, of E-POSS by 65% than microfibers with the adsorbed ammonia. The molecular mechanics model calculations, which were made using silica as a template, have shown that approximately two-layered APTES coating can be built on the model surface if complete hydrolysis of ethoxy groups and vertical condensation of APTES species are assumed. (en)
Title
  • Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay
  • Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay (en)
  • Vznik povrchové dvojvrstvy (3-aminopropyl)triethoxysilanu-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilsesviioxanu prostřednictvím skleněných mikrovláken s povrchem tvořeným systémem kyselina/zásada (cs)
skos:prefLabel
  • Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay
  • Surface-deposited acid/base on glass microfibers in formation of (3-aminopropyl)triethoxysilane-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloctasilsesquioxane bioverlay (en)
  • Vznik povrchové dvojvrstvy (3-aminopropyl)triethoxysilanu-[2-(3,4-epoxycyclohexyl)ethyl]heptaisobutyloktasilsesviioxanu prostřednictvím skleněných mikrovláken s povrchem tvořeným systémem kyselina/zásada (cs)
skos:notation
  • RIV/61389013:_____/06:00032080!RIV06-AV0-61389013
http://linked.open.../vavai/riv/strany
  • 3633;3639
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/02/1327), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 502563
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/06:00032080
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • silanization; (3-amonipropyl)triethoxysilanes; epoxycyclohexylisobutyl polyhedral oligomeric silsesquioxane (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [6076AD740FA0]
http://linked.open...i/riv/nazevZdroje
  • Langmuir
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 22
http://linked.open...iv/tvurceVysledku
  • Dybal, Jiří
  • Tishchenko, Galina
  • Sedláková, Zdeňka
  • Bastl, Zdeněk
  • Brus, Jiří
  • Pekárek, Michal
  • Bleha, Miroslav
http://linked.open...n/vavai/riv/zamer
issn
  • 0743-7463
number of pages
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