About: 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials     Goto   Sponge   NotDistinct   Permalink

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  • This contribution reports new methodology we have developed for the disassembly of 3-D UTL framework into 2-D lamellae followed by structure modification including pillaring. This may be widely applicable, particularly to other zeolites that have D4R units present, and so should have great impact also on other porous solids. Specifically, controlled hydrolysis of D4R units in the interlayer space provides individual ultrathin layers with UTL structure by a chemically selective method. Further manipulation of the layers gives a completely novel approach (3D to 2D to pillared) offering hitherto unprecedented opportunities for the preparation of modified zeolites with diverse chemical and structural properties.
  • This contribution reports new methodology we have developed for the disassembly of 3-D UTL framework into 2-D lamellae followed by structure modification including pillaring. This may be widely applicable, particularly to other zeolites that have D4R units present, and so should have great impact also on other porous solids. Specifically, controlled hydrolysis of D4R units in the interlayer space provides individual ultrathin layers with UTL structure by a chemically selective method. Further manipulation of the layers gives a completely novel approach (3D to 2D to pillared) offering hitherto unprecedented opportunities for the preparation of modified zeolites with diverse chemical and structural properties. (en)
Title
  • 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials
  • 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials (en)
skos:prefLabel
  • 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials
  • 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials (en)
skos:notation
  • RIV/61388955:_____/13:00422330!RIV14-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GA203/08/0604), P(GAP106/12/0189)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 119809
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/13:00422330
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ultrathin zeolites; UTL zeolite; IPC-1PI (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [0E6EE8EFB8FA]
http://linked.open...i/riv/nazevZdroje
  • Chemistry of Materials
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 25
http://linked.open...iv/tvurceVysledku
  • Zukal, Arnošt
  • Čejka, Jiří
  • Shvets, O. V.
  • Chlubná, Pavla
  • Roth, Wieslaw Jerzy
  • Morris, R. E.
  • Greer, H. F.
  • Zhou, W.
http://linked.open...ain/vavai/riv/wos
  • 000315618500005
issn
  • 0897-4756
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/cm303260z
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