About: Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution.

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About: Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A multivariate curve resolution method by alternating least squares is applied to differential pulse voltammograms measured on the Cd(II)+(.gamma.-Glu-Cys)2 Gly system as a model of metal-phytochelatin interactions. The combined analysis of both matrices from titrations of peptide with metal and of metal with peptide (concentration range 10-7 to 10-5 mol1-1) allowed the resolution of the system. The analysis of the resulting pure voltammograms and concentration profiles of the resolved components suggested the presence of four different types of bound Cd(II) and made possible the formulation of a complexation model. A multivariate curve resolution method by alternating least squares is applied to differential pulse voltammograms measured on the Cd(II)+(.gamma.-Glu-Cys)2 Gly system as a model of metal-phytochelatin interactions. The combined analysis of both matrices from titrations of peptide with metal and of metal with peptide (concentration range 10-7 to 10-5 mol1-1) allowed the resolution of the system. The analysis of the resulting pure voltammograms and concentration profiles of the resolved components suggested the presence of four different types of bound Cd(II) and made possible the formulation of a complexation model. (en)
Title	Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. (en)
skos:prefLabel	Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. (en)
skos:notation	RIV/61388955:_____/02:54020011!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	111;118
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GV204/97/K084), Z(AV0Z4040901), Z(AV0Z4055905)
http://linked.open...iv/cisloPeriodika	1/2
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Šestáková, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	643149
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/02:54020011
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	heavy metal speciation; - cadmium; - voltammetry (en)
http://linked.open.../riv/klicoveSlovo	- cadmium - voltammetry heavy metal speciation
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[24E15754D813]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Electrodes modified with nucleic acids and proteins.New tools in biochemical and biomedical research.
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	520
http://linked.open...iv/tvurceVysledku	Šestáková, Ivana Velek, Jiří Esteban, M. Arino, Ch. Cruz, B. H. Diaz-Cruz, J. M.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů Chemical principles of selected biological phenomena in medicine and ecology
issn	0022-0728
number of pages	8 (xsd:int)

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