About: Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Experimentální a teoretické studie prvních vanadocenových komplexů alfa-aminokyselin připravených z vanadocendichloridu (cs) The first bioinorganic vanadocene(IV) complexes of alpha-amino acids ([Cp2V(aa)]Cl, Cp = eta(5)-C5H5, aa = glycine, L-alanine, L- valine) were prepared by reaction of vanadocene dichloride ([Cp2VCl2]) and alpha-amino acids in aqueous methanol. Analogous cationic complexes with PF6- counterions were obtained by metathetical reactions of the chloride precursors with KPF6. These compounds are of great interest as model systems for the vanadocene moiety binding to proteins. All complexes have been characterized by elemental analyses and IR, Raman and EPR spectroscopies. On the basis of EPR spectra, a chelate in all the studied complexes was proposed, formed by the carboxylato and amino groups. This structure has also been confirmed by density functional theory (DFT) calculations. The first bioinorganic vanadocene(IV) complexes of alpha-amino acids ([Cp2V(aa)]Cl, Cp = eta(5)-C5H5, aa = glycine, L-alanine, L- valine) were prepared by reaction of vanadocene dichloride ([Cp2VCl2]) and alpha-amino acids in aqueous methanol. Analogous cationic complexes with PF6- counterions were obtained by metathetical reactions of the chloride precursors with KPF6. These compounds are of great interest as model systems for the vanadocene moiety binding to proteins. All complexes have been characterized by elemental analyses and IR, Raman and EPR spectroscopies. On the basis of EPR spectra, a chelate in all the studied complexes was proposed, formed by the carboxylato and amino groups. This structure has also been confirmed by density functional theory (DFT) calculations. (en)
Title	Experimentální a teoretické studie prvních vanadocenových komplexů alfa-aminokyselin připravených z vanadocendichloridu (cs) Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride (en)
skos:prefLabel	Experimentální a teoretické studie prvních vanadocenových komplexů alfa-aminokyselin připravených z vanadocendichloridu (cs) Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride Experimental and theoretical study of the first vanadocene(IV) complexes of alpha-amino acids prepared from vanadocene dichloride (en)
skos:notation	RIV/00216275:25310/04:00001638!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	811-821
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 253100001)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Vinklárek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	563684
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/04:00001638
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	vanadocene dichloride; metallocenes; vanadium; amino acids; antitumor activity; EPR spectroscopy; density functional theory; DFT calculations (en)
http://linked.open.../riv/klicoveSlovo	vanadocene dichloride EPR spectroscopy metallocenes DFT calculations amino acids density functional theory vanadium antitumor activity
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[8B38F1702256]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Cimmunications
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2004
http://linked.open...v/svazekPeriodika	69
http://linked.open...iv/tvurceVysledku	Vinklárek, Jaromír Honzíček, Jan Paláčková, Hana
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20253100001
issn	0010-0765
number of pages	11 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 91 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software