About: Synthesis and evolution of crystalline garnet phases in Y3Sc5-xGaxO12     Goto   Sponge   NotDistinct   Permalink

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  • Mixed-metal oxides with the composition Y3ScxGa5xO12 (x 2.0, 2.1, 2.2, 2.25,2.3, 2.4, 2.5, and 3.0) have been prepared by an aqueous solgel method. The effects of scandium substitution on the garnet phase formation were studied by IR spectroscopy and X-ray powder diffraction (XRD). The XRD data indicate that single-phase Y3ScxGa5-xO12 ceramic samples were obtained for x-2.0, 2.1, 2.2, 2.25, 2.3, and 2.4. The results also show that the formation of Y3ScxGa5-xO12 garnets depends on the molar ratio of scandium and gallium in the investigated composition, and consequently on the mean cationic radius at the Al3+ sites. The variation of lattice parameters for the Y3ScxGa5-xO12 phases with different x is reported.
  • Mixed-metal oxides with the composition Y3ScxGa5xO12 (x 2.0, 2.1, 2.2, 2.25,2.3, 2.4, 2.5, and 3.0) have been prepared by an aqueous solgel method. The effects of scandium substitution on the garnet phase formation were studied by IR spectroscopy and X-ray powder diffraction (XRD). The XRD data indicate that single-phase Y3ScxGa5-xO12 ceramic samples were obtained for x-2.0, 2.1, 2.2, 2.25, 2.3, and 2.4. The results also show that the formation of Y3ScxGa5-xO12 garnets depends on the molar ratio of scandium and gallium in the investigated composition, and consequently on the mean cationic radius at the Al3+ sites. The variation of lattice parameters for the Y3ScxGa5-xO12 phases with different x is reported. (en)
Title
  • Synthesis and evolution of crystalline garnet phases in Y3Sc5-xGaxO12
  • Synthesis and evolution of crystalline garnet phases in Y3Sc5-xGaxO12 (en)
skos:prefLabel
  • Synthesis and evolution of crystalline garnet phases in Y3Sc5-xGaxO12
  • Synthesis and evolution of crystalline garnet phases in Y3Sc5-xGaxO12 (en)
skos:notation
  • RIV/00216224:14310/05:00013016!RIV10-GA0-14310___
http://linked.open...avai/riv/aktivita
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  • P(GA203/04/0296)
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  • 11
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  • 545707
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  • RIV/00216224:14310/05:00013016
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  • Mixed-metal oxides; garnets; scandium substitution (en)
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [9025A021DAB2]
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  • Philosophical Magazine Letters
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  • 85
http://linked.open...iv/tvurceVysledku
  • Moravec, Zdeněk
  • Pinkas, Jiří
  • Kareiva, Aivaras
  • Mathur, Sanjay
  • Garskaite, Edita
  • Kazlauskas, R.
issn
  • 0950-0839
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  • 14310
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