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Description
| - New N-triazinyl derivatives were synthesized by reaction of cyanuric chloride with 1- and 9-aminoanthracenes and subsequent nucleophilic substitution of chlorine atoms on triazinyl ring with methoxy and/or phenylamino groups. The compounds were characterized by H-1 and C-13 NMR and mass spectra. The influence of the chemical structure and solvent polarity on the UV/Vis absorption and fluorescence spectra and fluorescence quantum yields were investigated. Semi-empirical computations revealed highly polar CT states in singlet excited state manifold connected with charge-transfer from the hydrocarbon moiety to the triazinyl ring. The relationships between the CT-to-emitting state energy gap, solvent polarity and fluorescence quantum yield were discussed.
- New N-triazinyl derivatives were synthesized by reaction of cyanuric chloride with 1- and 9-aminoanthracenes and subsequent nucleophilic substitution of chlorine atoms on triazinyl ring with methoxy and/or phenylamino groups. The compounds were characterized by H-1 and C-13 NMR and mass spectra. The influence of the chemical structure and solvent polarity on the UV/Vis absorption and fluorescence spectra and fluorescence quantum yields were investigated. Semi-empirical computations revealed highly polar CT states in singlet excited state manifold connected with charge-transfer from the hydrocarbon moiety to the triazinyl ring. The relationships between the CT-to-emitting state energy gap, solvent polarity and fluorescence quantum yield were discussed. (en)
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Title
| - N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties
- N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties (en)
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skos:prefLabel
| - N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties
- N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties (en)
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skos:notation
| - RIV/68407700:21340/13:00218818!RIV15-GA0-21340___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/68407700:21340/13:00218818
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - quenching; quantum yield; fluorescence spectra; synthesis; N-Triazinyl aminoanthracenes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dvořák, Miroslav
- Almonasy, N.
- Michl, Martin
- Bureš, F.
- Nepraš, M.
- Čermák, J.
- Přichystalová, H.
- Burgert, L.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1007/s10895-013-1156-3
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http://localhost/t...ganizacniJednotka
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