| Attributes | Values |
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| rdf:type
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| Description
| - 6 funkcionálních polymerů gelového typu, z toho 3 různě zesítěné poly-DMAA-co-TMPTP (DMAA=N,N-dimethylakrylamid, TMPTP=trimethylolpropyltrimethakrylát) a 3 poly-DMAA-co-MA-co-TMPTP (MA= kyselina methakfylová) byly po zbobtnání ve vodě a jiných rozpustidlech zkoumány pomocí ISEC (inverzní sterické exkluzní chromatografie), a ESR a CP-MAS 13C NMR spektroskopie. Tato kombinace koncepčně nezávislých fyzikálně-chemických technik poskytla konzistentní představu o morfologii zkoumaných materiálů. (cs)
- Six gel-type functional resins, that is, three poly-DMAA-co-TMPTP (DMAA=N,N-dimethylacrylamide, TMPTP=trimethylolpropyltrimethacrylate) samples with different degrees of cross-linking (0.6, 1.2, 1.7 % mol) and three poly-DMAA-co-MA-co-TMPTP (MA=methacrylic acid, ca. 5.5 % mol) samples with 1.7, 3.5, and 7 % mol cross-linking were investigated with ISEC (inverse steric exclusion chromatography), and ESR and CP-MAS (cross polarization magic angle spinning) 13C NMR spectroscopy after swelling in water and other solvents. This unprecedented combination of conceptually independent physicochemical techniques provides a thorough overall consistent picture of the morphology of the resins on the nanometer scale and of the molecular accessibility of the swollen polymer framework to the paramagnetic probe TEMPONE (2,2,6,6-tetramethyl-4-oxo-1-oxypiperidine) and to selected solvents.
- Six gel-type functional resins, that is, three poly-DMAA-co-TMPTP (DMAA=N,N-dimethylacrylamide, TMPTP=trimethylolpropyltrimethacrylate) samples with different degrees of cross-linking (0.6, 1.2, 1.7 % mol) and three poly-DMAA-co-MA-co-TMPTP (MA=methacrylic acid, ca. 5.5 % mol) samples with 1.7, 3.5, and 7 % mol cross-linking were investigated with ISEC (inverse steric exclusion chromatography), and ESR and CP-MAS (cross polarization magic angle spinning) 13C NMR spectroscopy after swelling in water and other solvents. This unprecedented combination of conceptually independent physicochemical techniques provides a thorough overall consistent picture of the morphology of the resins on the nanometer scale and of the molecular accessibility of the swollen polymer framework to the paramagnetic probe TEMPONE (2,2,6,6-tetramethyl-4-oxo-1-oxypiperidine) and to selected solvents. (en)
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| Title
| - Gel-Type Polyacrylic Resins Cross-Linked with Trimethylolpropanetrimethacrylate: The Issue of Their Nanostructure and Molecular Accessibility Unveiled with a Combination of Inverse Steric Exclusion Chromatography (ISEC), and ESR and CP-MAS 13C NMR Spe...
- Gel-Type Polyacrylic Resins Cross-Linked with Trimethylolpropanetrimethacrylate: The Issue of Their Nanostructure and Molecular Accessibility Unveiled with a Combination of Inverse Steric Exclusion Chromatography (ISEC), and ESR and CP-MAS 13C NMR Spe... (en)
- Gelové polyakrylátové polymery zesítěné Trimethylolpropantrimetakrylátem: Nanostructura and molekulární dostupnost hodnocená kombinací inverzní sterické exkluzní chromatografie (ISEC), a ESR a CP-MAS 13C NMR spektroskopií (cs)
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| skos:prefLabel
| - Gel-Type Polyacrylic Resins Cross-Linked with Trimethylolpropanetrimethacrylate: The Issue of Their Nanostructure and Molecular Accessibility Unveiled with a Combination of Inverse Steric Exclusion Chromatography (ISEC), and ESR and CP-MAS 13C NMR Spe...
- Gel-Type Polyacrylic Resins Cross-Linked with Trimethylolpropanetrimethacrylate: The Issue of Their Nanostructure and Molecular Accessibility Unveiled with a Combination of Inverse Steric Exclusion Chromatography (ISEC), and ESR and CP-MAS 13C NMR Spe... (en)
- Gelové polyakrylátové polymery zesítěné Trimethylolpropantrimetakrylátem: Nanostructura and molekulární dostupnost hodnocená kombinací inverzní sterické exkluzní chromatografie (ISEC), a ESR a CP-MAS 13C NMR spektroskopií (cs)
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| skos:notation
| - RIV/67985858:_____/05:00028941!RIV06-AV0-67985858
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(KSK4050111), Z(AV0Z40720504)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/67985858:_____/05:00028941
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - functional resins; nanostructures; epr spectroscopy (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Chemistry European Journal
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Jeřábek, Karel
- Corain, B.
- Sassi, A.
- Lora, S.
- D'Archivio, A. A.
- Pace, G.
- Grassi, A.
- Pozzar, F.
|
| http://linked.open...n/vavai/riv/zamer
| |
| issn
| |
| number of pages
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| is http://linked.open...avai/riv/vysledek
of | |
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