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Description
| - The first nitration of codeine by using bismuth nitrate pentahydrate under mild reaction conditions is described. The resulting 1-nitrocodeine was reduced to 1-aminocodeine, a key precursor for the synthesis of the azo derivative and several hydrazones. Structures of both 1-nitrocodeine and 1-amino-codeine were unequivocally determined by single-crystal Xray analysis. The reported preliminary synthetic study lays the groundwork for the synthesis of modified codeine derivatives with potential biological activity.
- The first nitration of codeine by using bismuth nitrate pentahydrate under mild reaction conditions is described. The resulting 1-nitrocodeine was reduced to 1-aminocodeine, a key precursor for the synthesis of the azo derivative and several hydrazones. Structures of both 1-nitrocodeine and 1-amino-codeine were unequivocally determined by single-crystal Xray analysis. The reported preliminary synthetic study lays the groundwork for the synthesis of modified codeine derivatives with potential biological activity. (en)
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Title
| - Synthesis of 1-Aminocodeine as a Synthon for Other Codeine Derivatives
- Synthesis of 1-Aminocodeine as a Synthon for Other Codeine Derivatives (en)
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skos:prefLabel
| - Synthesis of 1-Aminocodeine as a Synthon for Other Codeine Derivatives
- Synthesis of 1-Aminocodeine as a Synthon for Other Codeine Derivatives (en)
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skos:notation
| - RIV/61989592:15310/13:33147715!RIV15-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(EE2.4.31.0130)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/13:33147715
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Synthetic methods / Drug design / Fused-ring systems / Diazo compounds / Isotopic labelling / Reduction (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - European Journal of Organic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Trávníček, Zdeněk
- Hradil, Pavel
- Popa, Igor
- Cankař, Petr
- Stýskala, Jakub
- Slouka, Jan
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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http://localhost/t...ganizacniJednotka
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