Description
| - The new complexes of nickel and copper with benzenetricarboxylic acid and with N-donor ligands and Schiff bases have been prepared: Ni3(bimz)6(btc)2.12H2O, Ni3(1,2,3-btz)(btc)2.12H2O, Ni2(C13H12NO)(btc).H2O, Ni3(C17H16N2O2)2(Hbtc).9H2O, Ni2(C13H9N2O3)(btc).4H2O, Cu3(pmdien)3(btc)(ClO4)3.6H2O, Cu2(C14H12NO2)(btc).7H2O and [Cu3(mdpta)3(btc)](ClO4)3.3H2O, where H3btc = 1,3,5-benzenetricarboxylic acid, 1,2,3-btz = 1,2,3-benztriazole, C13H11NO = 2-[(phenylimino)methyl]phenol, C17H18N2O2 = N,N'-bis(salicylidene)propylenediamine, C13H10N2O3 = 2-{[(2-nitrophenyl)methyl]phenol, pmdien = N,N,N',N',N''- pentamethyldiethylenetriamine, C14H13NO2 = 2-[(4-methoxyphenylimino)methyl]phenol and mdpta = N,N-bis(3-aminopropyl)methylamine. The prepared complexes have been characterized by elemental analysis, UV-VIS and IR spectroscopy and thermal analysis (at selected compounds). (en)
- Byly připraveny původní komplexy niklu a mědi s benzentrikarboxylovou kyselinou v kombinaci s N-donorovými ligandy a Schiffovými bázemi: Ni3(bimz)6(btc)2.12H2O, Ni3(1,2,3-btz)(btc)2.12H2O, Ni2(C13H10NO)(btc).H2O, Ni3(C17H16N2O2)2(Hbtc).9H2O, Ni2(C13H9N2O3)(btc).4H2O, Cu3(pmdien)3(btc)(ClO4)3.6H2O, Cu2(C14H12NO2)(btc).7H2O and [Cu3(mdpta)3(btc)](ClO4)3.3H2O, kde H3btc = kyselina benzen-1,3,5-trikarboxylová, 1,2,3-btz = 1,2,3-benztriazol, C13H11NO = 2-[(fenylimino)methyl]fenol, C17H18N2O2 = N,N´-bis(salicyliden)propylendiamin, C13H10N2O3 = 2-{[(2-nitrofenyl)methylen]amino}fenol, pmdien = N,N,N',N'',N''-pentamethyldiethylentriamin, C14H13NO2 = 2-[(4-methoxyfenylimino)methyl]fenol a mdpta = N,N-bis(3-aminopropyl)methylamin. Připravené komplexy byly podrobeny elementární analýze a dále studovány UV-VIs a IR spektroskopií a u vybraných látek termickou analýzou.
- Byly připraveny původní komplexy niklu a mědi s benzentrikarboxylovou kyselinou v kombinaci s N-donorovými ligandy a Schiffovými bázemi: Ni3(bimz)6(btc)2.12H2O, Ni3(1,2,3-btz)(btc)2.12H2O, Ni2(C13H10NO)(btc).H2O, Ni3(C17H16N2O2)2(Hbtc).9H2O, Ni2(C13H9N2O3)(btc).4H2O, Cu3(pmdien)3(btc)(ClO4)3.6H2O, Cu2(C14H12NO2)(btc).7H2O and [Cu3(mdpta)3(btc)](ClO4)3.3H2O, kde H3btc = kyselina benzen-1,3,5-trikarboxylová, 1,2,3-btz = 1,2,3-benztriazol, C13H11NO = 2-[(fenylimino)methyl]fenol, C17H18N2O2 = N,N´-bis(salicyliden)propylendiamin, C13H10N2O3 = 2-{[(2-nitrofenyl)methylen]amino}fenol, pmdien = N,N,N',N'',N''-pentamethyldiethylentriamin, C14H13NO2 = 2-[(4-methoxyfenylimino)methyl]fenol a mdpta = N,N-bis(3-aminopropyl)methylamin. Připravené komplexy byly podrobeny elementární analýze a dále studovány UV-VIs a IR spektroskopií a u vybraných látek termickou analýzou. (cs)
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