Description
| - The new complex compounds of composition [Ni(en)2(mnt)] (I), [Ni(1,2-dap)2 (mnt)].H2O (II), [Ni(n-phen)(mnt)] (III), [Ni2(4,4#-bpy)4(mnt)2Cl(H2O)2].2H2O (IV), [Ni(dpp)(mnt)].H2O (V); [Co(phen)(mnt)].H2O (VI), [Co(dppe)(mnt)].2H2O (VII) and (Me3PhN)2[Ni(mnt)2] (VIII) (en = ethylenediamine, 1,2-dap = 1,2-diaminopropane, n-phen = 5-nitro-1,10-phenanthroline, bpy = bipyridine, mnt2# = maleonitriledithiolate, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino) propane, Me3PhN+ = trimethylphenylammonium) have been synthesized and studied by common physico-chemical measurements. For compound VIII, the X-ray structure was solved, which confirms the nearly square coordination around the central atom in the NiS4 chromophore.
- The new complex compounds of composition [Ni(en)2(mnt)] (I), [Ni(1,2-dap)2 (mnt)].H2O (II), [Ni(n-phen)(mnt)] (III), [Ni2(4,4#-bpy)4(mnt)2Cl(H2O)2].2H2O (IV), [Ni(dpp)(mnt)].H2O (V); [Co(phen)(mnt)].H2O (VI), [Co(dppe)(mnt)].2H2O (VII) and (Me3PhN)2[Ni(mnt)2] (VIII) (en = ethylenediamine, 1,2-dap = 1,2-diaminopropane, n-phen = 5-nitro-1,10-phenanthroline, bpy = bipyridine, mnt2# = maleonitriledithiolate, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino) propane, Me3PhN+ = trimethylphenylammonium) have been synthesized and studied by common physico-chemical measurements. For compound VIII, the X-ray structure was solved, which confirms the nearly square coordination around the central atom in the NiS4 chromophore. (en)
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