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rdf:type
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Description
| - The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions.
- The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions. (en)
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Title
| - Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
- Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) (en)
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skos:prefLabel
| - Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
- Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) (en)
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skos:notation
| - RIV/61989592:15310/01:00001648!RIV/2003/MSM/153103/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/01:00001648
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - copper(II); iron(II); cyanide-bridged complexes; diamines; nitroprussides; cyanides; magnetic properties; crystal structure (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Collection of Czechoslovak Chemical Communications
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Smékal, Zdeněk
- Svoboda, Ingrid
- Kameníček, Jiří
- Escuer, Albert
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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