About: Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N ''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid)     Goto   Sponge   Distinct   Permalink

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Description
  • Ni-II mixed-ligand complexes of compositions [Ni(pmdien)(ttcH)] (1), [Ni(baphen)(2)(ttcH)] . 4H(2)O (2), [Ni-(dpa)(ttcH)(H2O)] (3), [Ni(cyclam)(ttcH)] . 2H(2)O (4), [Ni(hexaa)](ttcH) (5) and [Ni(hexab)(ttcH)] . 2H(2)O (6), (baphen = 4,7-diphenyl-1,10-phenanthroline, dpa = 2,2'-dipyridylamine, cyclam = 1,4,8,11-tetraazacyclotetradecane, hexaa = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6),9]-octadecane, hexab = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane) have been prepared and characterized by meansof i.r., u.v.-vis. spectroscopies and magnetochemical measurements. The redox properties of the complexes were studied by cyclic voltammetry. The crystal and molecular structure of [Ni(pmdien)(ttcH)] was determined. The nickel atom is penta-coordinated by three N atoms of pmdien, and by S and N atoms of trithiocyanurate(2-) anion.
  • Ni-II mixed-ligand complexes of compositions [Ni(pmdien)(ttcH)] (1), [Ni(baphen)(2)(ttcH)] . 4H(2)O (2), [Ni-(dpa)(ttcH)(H2O)] (3), [Ni(cyclam)(ttcH)] . 2H(2)O (4), [Ni(hexaa)](ttcH) (5) and [Ni(hexab)(ttcH)] . 2H(2)O (6), (baphen = 4,7-diphenyl-1,10-phenanthroline, dpa = 2,2'-dipyridylamine, cyclam = 1,4,8,11-tetraazacyclotetradecane, hexaa = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6),9]-octadecane, hexab = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane) have been prepared and characterized by meansof i.r., u.v.-vis. spectroscopies and magnetochemical measurements. The redox properties of the complexes were studied by cyclic voltammetry. The crystal and molecular structure of [Ni(pmdien)(ttcH)] was determined. The nickel atom is penta-coordinated by three N atoms of pmdien, and by S and N atoms of trithiocyanurate(2-) anion. (en)
Title
  • Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N ''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid)
  • Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N ''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid) (en)
skos:prefLabel
  • Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N ''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid)
  • Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N ''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid) (en)
skos:notation
  • RIV/61989592:15310/01:00001537!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany
  • 282-286
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/98/P220), Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 676456
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/01:00001537
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • MOLECULAR-STRUCTURE; COMPLEXES; CRYSTAL (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [49DA7E2858B0]
http://linked.open...i/riv/nazevZdroje
  • Transition Metal Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 26
http://linked.open...iv/tvurceVysledku
  • Kvítek, Libor
  • Marek, Jaromír
  • Trávníček, Zdeněk
  • Kopel, Pavel
  • Biler, Martin
  • Pavlíček, Marek
http://linked.open...n/vavai/riv/zamer
issn
  • 0340-4285
number of pages
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  • 15310
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