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  • Recent developments in SERS (surface-enhanced Raman scattering) and SERRS (surface-enhanced resonance Raman scattering) spectroscopy are related to the discovery of its single molecule sensitivity. The achievement of single molecule level of SERS and/or SERRS spectral detection is understood to be conditioned by localization of detected molecules into unusually strong nanoscale-localized optical fields (dubbed hot spots). Recent calculations predict SERS enhancement factors as high as 1 x 1015 for certain chromophoric molecules located in the hot spot between two Ag nanoparticles [P. Johansson, H. Xu, M. Kall, Phys. Rev. B 72 (2005) 035427.]. Owing to a combination of single molecule sensitivity with the fingerprint selectivity inherent to vibrational spectroscopy, single molecule SERS spectroscopy can potentially offer unprecedented possibilities of analytical applications.
  • Recent developments in SERS (surface-enhanced Raman scattering) and SERRS (surface-enhanced resonance Raman scattering) spectroscopy are related to the discovery of its single molecule sensitivity. The achievement of single molecule level of SERS and/or SERRS spectral detection is understood to be conditioned by localization of detected molecules into unusually strong nanoscale-localized optical fields (dubbed hot spots). Recent calculations predict SERS enhancement factors as high as 1 x 1015 for certain chromophoric molecules located in the hot spot between two Ag nanoparticles [P. Johansson, H. Xu, M. Kall, Phys. Rev. B 72 (2005) 035427.]. Owing to a combination of single molecule sensitivity with the fingerprint selectivity inherent to vibrational spectroscopy, single molecule SERS spectroscopy can potentially offer unprecedented possibilities of analytical applications. (en)
Title
  • Single molecule SERS: Perspectives of analytical applications
  • Single molecule SERS: Perspectives of analytical applications (en)
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  • Single molecule SERS: Perspectives of analytical applications
  • Single molecule SERS: Perspectives of analytical applications (en)
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  • RIV/61389013:_____/07:00340259!RIV10-AV0-61389013
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  • P(GA203/04/0688), Z(AV0Z40500505)
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  • RIV/61389013:_____/07:00340259
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  • surface-enhanced Raman scattering (SERS); surface-enhanced resonance Raman (SERRS); single molecule SERS (en)
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  • NL - Nizozemsko
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  • [0754CC659B7C]
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  • Journal of Molecular Structure
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  • 834-836
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  • Šlouf, Miroslav
  • Šišková, K.
  • Vlčková, B.
  • Pavel, I.
  • Sládková, M.
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  • 000246329200006
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  • 0022-2860
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