About: High-temperature stability, structure and thermoelectric propertiesof CaMn1-xNbxO3 phases     Goto   Sponge   Distinct   Permalink

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  • Polycrystalline perovskite-type CaMn1-xNbxO3 phases (with x = 0.02, 0.05, 0.08 and 0.10) were investigated with regard to their structure, microstructure and thermal stability as a function of temperature. A possible mechanism relating the high-temperature structural transition and the thermal reduction process of slightly substituted CaMnO3 phases was proposed. The thermal reduction process resulted in a change in the Mn3+/Mn4+ concentrations in the Mn sublattice, and therefore in a modification of the transport properties. A comprehensive study examined the impact of both phenomena on the electrical and thermal transport properties.
  • Polycrystalline perovskite-type CaMn1-xNbxO3 phases (with x = 0.02, 0.05, 0.08 and 0.10) were investigated with regard to their structure, microstructure and thermal stability as a function of temperature. A possible mechanism relating the high-temperature structural transition and the thermal reduction process of slightly substituted CaMnO3 phases was proposed. The thermal reduction process resulted in a change in the Mn3+/Mn4+ concentrations in the Mn sublattice, and therefore in a modification of the transport properties. A comprehensive study examined the impact of both phenomena on the electrical and thermal transport properties. (en)
Title
  • High-temperature stability, structure and thermoelectric propertiesof CaMn1-xNbxO3 phases
  • High-temperature stability, structure and thermoelectric propertiesof CaMn1-xNbxO3 phases (en)
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  • High-temperature stability, structure and thermoelectric propertiesof CaMn1-xNbxO3 phases
  • High-temperature stability, structure and thermoelectric propertiesof CaMn1-xNbxO3 phases (en)
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  • RIV/61388980:_____/09:00336243!RIV10-MSM-61388980
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  • P(GA203/09/1036), P(LC523), Z(AV0Z10100521), Z(AV0Z40320502)
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  • 19
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  • 317185
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  • RIV/61388980:_____/09:00336243
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  • perovskites; thermoelectricity; structural transition; thermal reduction; twinned domain microstructure (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [D25AF5E29D68]
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  • Acta Materialia
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  • 57
http://linked.open...iv/tvurceVysledku
  • Bakardjieva, Snejana
  • Hejtmánek, Jiří
  • Aguirre, M. H.
  • Logvinovich, D.
  • Weidenkaff, A.
  • Bocher, L.
  • Robert, R.
http://linked.open...ain/vavai/riv/wos
  • 000271668200005
http://linked.open...n/vavai/riv/zamer
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  • 1359-6454
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