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rdf:type
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Description
| - Byly pozorovány výrazné oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu, lišící se v parametrech a v reakčních podmínkách od oscilačního chování popsaného dříve pro tuto reakci na Fe-zeolitech. Tyto pozorované pravidelné oscilace v konverzi N2O byly doprovázeny pravidelnými oscilacemi v rychlosti vzniku N2 a O2, a to v suché reakční směsi N2O/He a byly reversibilně zhášeny přídavkem NO/NO2 do směsi. Tyto jevy byly pozorovány v rozsahu teplot 400-450oC pro Fe/Pt-ferrierit, s periodami v rozsahu 0.5-3.5 min. Pro Fe-ferrierit byl teplotní rozsah oscilačního chování posunut k vyšším teplotám (t.j. 450-500oC). Na rozdíl od Fe/Pt-ferrieritu, se perioda oscilací na Fe-ferrieritu prakticky neměnila s teplotou. Tvar oscilací na obou katalyzátorech byl složitý a závisel na reakčních podmínkách. (cs)
- Well-expressed oscillation of the N2O decomposition over Fe- and Fe/Pt-ferrierite catalysts has been observed, differing both in parameters and conditions from the oscillation behavior described previously for the same reaction over Fe-zeolites. The observed regular oscillation in the N2O conversion was accompanied by changes on N2 and O2 production in a dry N2O/He gas stream and was quenched reversibly after NO/NO2 addition. The results were observed in the temperature region 400-450oC over Fe/Pt-ferrierite, with periods of 0.5-3.5 min. For Fe-ferrierite, the temperature region for the oscillation behavior was sliághtly higher (i.e. 450-500oC). In triking contrast to Fe/Pt-ferrierite, the period of oscillation did not change with temperature over Fe-ferrierite. The patterns of the oscillation over both catalysts were complex and depended on the reaction conditions.
- Well-expressed oscillation of the N2O decomposition over Fe- and Fe/Pt-ferrierite catalysts has been observed, differing both in parameters and conditions from the oscillation behavior described previously for the same reaction over Fe-zeolites. The observed regular oscillation in the N2O conversion was accompanied by changes on N2 and O2 production in a dry N2O/He gas stream and was quenched reversibly after NO/NO2 addition. The results were observed in the temperature region 400-450oC over Fe/Pt-ferrierite, with periods of 0.5-3.5 min. For Fe-ferrierite, the temperature region for the oscillation behavior was sliághtly higher (i.e. 450-500oC). In triking contrast to Fe/Pt-ferrierite, the period of oscillation did not change with temperature over Fe-ferrierite. The patterns of the oscillation over both catalysts were complex and depended on the reaction conditions. (en)
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Title
| - Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition
- Isothermální oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu (cs)
- Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition (en)
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skos:prefLabel
| - Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition
- Isothermální oscilace při rozkladu N2O na katalyzátorech na bázi Fe- a Fe/Pt-ferrieritu (cs)
- Isothermal oscillation during N2O decomposition over Fe- and Fe/Pt-ferrierite: Effect of NO addition (en)
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skos:notation
| - RIV/61388955:_____/06:00040531!RIV07-AV0-61388955
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GP104/02/D124), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/06:00040531
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Fe-ferrierite; Fe/Pt-ferrierite; N2O decomposition; oscillation (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Nováková, Jana
- Sobalík, Zdeněk
- Kaucký, Dalibor
- Jíša, Kamil
- Vondrová, Alena
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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