About: Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate

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About: Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate Goto Sponge Distinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Cyclopentadiene was lithiated with BuLi and then reacted with 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctane to afford (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Repeated lithiation with BuLi, followed by addition of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl triflate yielded the target bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene in a good yield as a mixture of four regioisomers. Cyclopentadiene was lithiated with BuLi and then reacted with 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctane to afford (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Repeated lithiation with BuLi, followed by addition of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl triflate yielded the target bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene in a good yield as a mixture of four regioisomers. (en) Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl)cyklopentadien. Příprava z cyklopenta-1,3-dienu, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridekafluor-8-jodoktanu a 3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl-triflátu (cs)
Title	Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl)cyklopentadien. Příprava z cyklopenta-1,3-dienu, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridekafluor-8-jodoktanu a 3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl-triflátu (cs) Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate (en)
skos:prefLabel	Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl)cyklopentadien. Příprava z cyklopenta-1,3-dienu, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridekafluor-8-jodoktanu a 3,3,4,4,5,5,6,6,7,7,8,8,8-tridekafluoroktyl-triflátu (cs) Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)cyclopentadiene. Preparation from Cyclopenta-1,3-diene, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane and 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl Triflate (en)
skos:notation	RIV/60461373:22310/04:00011358!RIV/2005/AV0/223105/N
http://linked.open.../vavai/riv/strany	452-454
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA4072203), Z(MSM 223100001)
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Bříza, Tomáš Kvíčala, Jaroslav Paleta, Oldřich
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	556386
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/04:00011358
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	fluorous;polyfluorinated;fluorophilic;cyclopentadiene;iodide;triflate (en)
http://linked.open.../riv/klicoveSlovo	iodide fluorous triflate cyclopentadiene fluorophilic polyfluorinated
http://linked.open...ontrolniKodProRIV	[2D3F69A262E4]
http://linked.open...i/riv/mistoVydani	Weinheim
http://linked.open...vEdiceCisloSvazku	Neuveden
http://linked.open...i/riv/nazevZdroje	Handbook of Ffluorous Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Novel fluorophilic ligands for transition metal complexes based on polyfluorinated
http://linked.open...UplatneniVysledku	2004
http://linked.open...iv/tvurceVysledku	Bříza, Tomáš Kvíčala, Jaroslav Paleta, Oldřich
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223100001
number of pages	595 (xsd:int)
http://purl.org/ne...btex#hasPublisher	WILEY-VCH
https://schema.org/isbn	3-527-30617-X
http://localhost/t...ganizacniJednotka	22310

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