About: Imperfections of Kissinger Evaluation Method and Crystallization Kinetics

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The famous Kissinger's kinetic evaluation method (Anal. Chem. 1957) is examined with respect to: a) the relation between the DTA signal théta (t) and the reaction rate r(t) ? dalfa/dt; b) the requirements on reaction mechanism model f(alfa); and c) the relation of starting kinetic equation to the equilibrium behavior of sample under study. Distorting effect of heat inertia and difference between the temperature Tp of extreme DTA deviation and the temperature Tm at which the reaction rate is maximal are revealed. The kinetic equations respecting the influence of equilibrium temperature Teq, especially fusion temperature Tf, are tested as bases for a modified Kissinger like evaluation of kinetics. The famous Kissinger's kinetic evaluation method (Anal. Chem. 1957) is examined with respect to: a) the relation between the DTA signal théta (t) and the reaction rate r(t) ? dalfa/dt; b) the requirements on reaction mechanism model f(alfa); and c) the relation of starting kinetic equation to the equilibrium behavior of sample under study. Distorting effect of heat inertia and difference between the temperature Tp of extreme DTA deviation and the temperature Tm at which the reaction rate is maximal are revealed. The kinetic equations respecting the influence of equilibrium temperature Teq, especially fusion temperature Tf, are tested as bases for a modified Kissinger like evaluation of kinetics. (en)
Title	Imperfections of Kissinger Evaluation Method and Crystallization Kinetics Imperfections of Kissinger Evaluation Method and Crystallization Kinetics (en)
skos:prefLabel	Imperfections of Kissinger Evaluation Method and Crystallization Kinetics Imperfections of Kissinger Evaluation Method and Crystallization Kinetics (en)
skos:notation	RIV/49777513:23640/14:43924277!RIV15-MSM-23640___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0088)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Šesták, Jaroslav Holba, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Západočeská univerzita v Plzni / Nové technologie - výzkumné centrum
http://linked.open...dnocenehoVysledku	20803
http://linked.open...ai/riv/idVysledku	RIV/49777513:23640/14:43924277
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	melting temperature; equilibrium temperature; crystallization; driving force; heat inertia; nonisothermal kinetics; Kissinger method; DTA (en)
http://linked.open.../riv/klicoveSlovo	DTA crystallization Kissinger method melting temperature nonisothermal kinetics driving force equilibrium temperature heat inertia
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[BE75A2405488]
http://linked.open...i/riv/nazevZdroje	Glass Physics and Chemistry
http://linked.open...in/vavai/riv/obor	BJ
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of the New Technologies and Materials
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	40
http://linked.open...iv/tvurceVysledku	Šesták, Jaroslav Holba, Pavel
http://linked.open...ain/vavai/riv/wos	000343722600002
issn	1087-6596
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1134/S1087659614050058
http://localhost/t...ganizacniJednotka	23640

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