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  • The history of knowledge on phase transitions character has been outlined. Following 1933 Ehrenfest's classification of phase transition the proposal for classification of processes indicated by thermal analysis is introduced. The equations -analogous to the Clapeyron and Ehrenfest ones- are derived to determine thermodynamic quantities accompanied with sharp and gradual transition. The equations utilize the slope of phase diagram curves. Similar equations are derived also for decomposition reactions under controlled atmosphere.
  • The history of knowledge on phase transitions character has been outlined. Following 1933 Ehrenfest's classification of phase transition the proposal for classification of processes indicated by thermal analysis is introduced. The equations -analogous to the Clapeyron and Ehrenfest ones- are derived to determine thermodynamic quantities accompanied with sharp and gradual transition. The equations utilize the slope of phase diagram curves. Similar equations are derived also for decomposition reactions under controlled atmosphere. (en)
Title
  • Equilibrium Background of Processes Initiated by Heating and Ehrenfest's Classification of Phase Transitions
  • Equilibrium Background of Processes Initiated by Heating and Ehrenfest's Classification of Phase Transitions (en)
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  • Equilibrium Background of Processes Initiated by Heating and Ehrenfest's Classification of Phase Transitions
  • Equilibrium Background of Processes Initiated by Heating and Ehrenfest's Classification of Phase Transitions (en)
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  • RIV/49777513:23640/13:43920940!RIV14-MSM-23640___
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  • 73146
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  • RIV/49777513:23640/13:43920940
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  • partially open systems; controlled atmosphere; Clapeyron equations; sharp & gradual phase transition; monotropic & enantiotropic processes; equilibrium background; thermal analysis; phase transitions (en)
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  • [82A6361655D1]
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  • Hot Topics in Thermal Analysis and Calorimetry 9
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  • Thermal Analysis of Micro, Nano- and Non-Crystalline Materials: Transformation, Crystalization, Kinetics and Thermodynamics
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  • Holba, Pavel
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  • Springer-Verlag
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  • 978-90-481-3149-5
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  • 23640
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