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Description
| - Various tri-, di- and monoorganotin(IV) catecholates were prepared independently by three different reaction pathways, e. g. elimination of a small molecule (lithium halide) from the conversion of organotin(IV) halide with lithium catecholate, condensation or protonolytic reactions of organotin(IV) oxide or hydride with catechol and reduction of a quinone by distannane, organotin(IV) hydride or stannylene. C,N-chelating 2-[(CH3)(2)NCH2]C6H4- = L-CN, bulky amido ([2,6-(Pr-i)C6H3](SiMe3)N- = L-N and amido-amino chelating ({2-[(CH3)(2)NCH2]C6H4}(SiMe3 or GePh3)N- = L-NN1 or L-NN2 ligands were used in this study. All tin(IV) catecholates reveal dimeric structures with six-coordinated tin atoms except for (L-CN)(2)Sn{(3,5-(t-Bu)(2)C6H2]-1,2-(O)(2))} which is monomeric due to the presence of two C,N-chelating ligands. All compounds, including two hydrolysis products, were characterized by a multinuclear NMR approach and X-ray diffraction techniques.
- Various tri-, di- and monoorganotin(IV) catecholates were prepared independently by three different reaction pathways, e. g. elimination of a small molecule (lithium halide) from the conversion of organotin(IV) halide with lithium catecholate, condensation or protonolytic reactions of organotin(IV) oxide or hydride with catechol and reduction of a quinone by distannane, organotin(IV) hydride or stannylene. C,N-chelating 2-[(CH3)(2)NCH2]C6H4- = L-CN, bulky amido ([2,6-(Pr-i)C6H3](SiMe3)N- = L-N and amido-amino chelating ({2-[(CH3)(2)NCH2]C6H4}(SiMe3 or GePh3)N- = L-NN1 or L-NN2 ligands were used in this study. All tin(IV) catecholates reveal dimeric structures with six-coordinated tin atoms except for (L-CN)(2)Sn{(3,5-(t-Bu)(2)C6H2]-1,2-(O)(2))} which is monomeric due to the presence of two C,N-chelating ligands. All compounds, including two hydrolysis products, were characterized by a multinuclear NMR approach and X-ray diffraction techniques. (en)
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Title
| - Preparation and structure of tin(IV) catecholates by reactions of C,N-chelated tin(IV) compounds with a catechol or lithium catecholate, and various stannylenes with a quinone
- Preparation and structure of tin(IV) catecholates by reactions of C,N-chelated tin(IV) compounds with a catechol or lithium catecholate, and various stannylenes with a quinone (en)
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skos:prefLabel
| - Preparation and structure of tin(IV) catecholates by reactions of C,N-chelated tin(IV) compounds with a catechol or lithium catecholate, and various stannylenes with a quinone
- Preparation and structure of tin(IV) catecholates by reactions of C,N-chelated tin(IV) compounds with a catechol or lithium catecholate, and various stannylenes with a quinone (en)
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skos:notation
| - RIV/00216275:25310/13:39896219!RIV14-GA0-25310___
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896219
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - XRD; NMR; catecholate; N-ligand; C; organotin(IV) compounds (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Padělková, Zdeňka
- Růžička, Aleš
- Turek, Jan
- Kampová, Hana
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.jorganchem.2013.07.025
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http://localhost/t...ganizacniJednotka
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