About: Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S0277538711006838
Description	Two new compounds containing decavanadate ions coordinated to copper centers, (2-hepH(+))(2)[{Cu (H2O)(2)(O,N-2-hep)}(2)V10O28]center dot 6H(2)O (2-hepH(+) = 2-(2-hydroxyethyl)pyridinium; 2-hep = 2-(2-hydroxyethyl) pyridine) (1), [{Cu(2-amp)(2)(H2O)}(2)H2V10O28]center dot 4H(2)O (amp = 2-(aminomethyl)pyridine) (2), have been prepared and characterized by elemental analyses and IR spectroscopy. The structure of 1 consists of trinuclear units [{Cu(H2O)(2)(O,N-2-hep)}(2)V10O28](2-), 2-hepH(+) cations and molecules of water of crystallization. A trinuclear unit [{Cu(2-amp)(2)(H2O)}(2)H2V10O28] is a principal part also in the structure of 2, but the bonds of decavanadate group to the copper complexes are much weaker than in 1. Two new compounds containing decavanadate ions coordinated to copper centers, (2-hepH(+))(2)[{Cu (H2O)(2)(O,N-2-hep)}(2)V10O28]center dot 6H(2)O (2-hepH(+) = 2-(2-hydroxyethyl)pyridinium; 2-hep = 2-(2-hydroxyethyl) pyridine) (1), [{Cu(2-amp)(2)(H2O)}(2)H2V10O28]center dot 4H(2)O (amp = 2-(aminomethyl)pyridine) (2), have been prepared and characterized by elemental analyses and IR spectroscopy. The structure of 1 consists of trinuclear units [{Cu(H2O)(2)(O,N-2-hep)}(2)V10O28](2-), 2-hepH(+) cations and molecules of water of crystallization. A trinuclear unit [{Cu(2-amp)(2)(H2O)}(2)H2V10O28] is a principal part also in the structure of 2, but the bonds of decavanadate group to the copper complexes are much weaker than in 1. (en)
Title	Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion (en)
skos:prefLabel	Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion (en)
skos:notation	RIV/00216275:25310/12:39895376!RIV13-MSM-25310___
http://linked.open...avai/predkladatel	Fakulta chemicko-technologická
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Padělková, Zdeňka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	172927
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895376
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	NMR spectra; X-ray structures; Copper complexes; decavanadate as ligand (en)
http://linked.open.../riv/klicoveSlovo	NMR spectra X-ray structures decavanadate as ligand Copper complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[E205BC5C9CB1]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	31
http://linked.open...iv/tvurceVysledku	Bartošová, Lenka Padělková, Zdeňka Schwendt, Peter Rakovský, Erik
http://linked.open...ain/vavai/riv/wos	000300642900073
issn	0277-5387
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.poly.2011.10.042
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion

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