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Description
  • Byla vyvinuta syntetická cesta k přípravě chirálních derivátů 2-fenylimidazolu a touto cestou bylo syntetizováno sedm chirálních derivátů 2-fenylimidazolu s chirálním centrem v řetězci v poloze 4. Syntéza vychází z dostupných chirálních aminokyselin. Koordinační sloučeniny mědi a připravených derivátů byly studovány jako chirální katalyzátory nitroaldolové kondenzace. (cs)
  • There have been developed a synthetic route for the preparation of chiral 2-phenylimidazole derivatives. This way have been prepared seven chiral derivatives of 2-phenylimidazole with chiral center placed in the chain bonded at position four. The synthesis start from readily available chiral amino acids. The complexes of copper (II) and prepared derivatives have been studied as potential chiral catalysts of nitroaldol condensation as well.
  • There have been developed a synthetic route for the preparation of chiral 2-phenylimidazole derivatives. This way have been prepared seven chiral derivatives of 2-phenylimidazole with chiral center placed in the chain bonded at position four. The synthesis start from readily available chiral amino acids. The complexes of copper (II) and prepared derivatives have been studied as potential chiral catalysts of nitroaldol condensation as well. (en)
Title
  • Chiral Imidazole Derivatives Synthesis from Enantiopure N-protected Aminoacids and Their Use in Asymmetric Catalysis.
  • Chiral Imidazole Derivatives Synthesis from Enantiopure N-protected Aminoacids and Their Use in Asymmetric Catalysis. (en)
  • Syntéza chirálních derivátů imidazolu z enantiomerně čistých N-chráněných aminokyselin a jejich využití v asymetrické katalýze. (cs)
skos:prefLabel
  • Chiral Imidazole Derivatives Synthesis from Enantiopure N-protected Aminoacids and Their Use in Asymmetric Catalysis.
  • Chiral Imidazole Derivatives Synthesis from Enantiopure N-protected Aminoacids and Their Use in Asymmetric Catalysis. (en)
  • Syntéza chirálních derivátů imidazolu z enantiomerně čistých N-chráněných aminokyselin a jejich využití v asymetrické katalýze. (cs)
skos:notation
  • RIV/00216275:25310/05:00002653!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 369-369
http://linked.open...avai/riv/aktivita
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  • Z(MSM0021627501)
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  • 515209
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  • RIV/00216275:25310/05:00002653
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  • Imidazole; aminoacids; catalysis; nitroaldol condensation (en)
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http://linked.open...ontrolniKodProRIV
  • [85D3BF895ACB]
http://linked.open...v/mistoKonaniAkce
  • Helsinki, Finsko
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  • Jyväskylä Finland
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  • 14th European Symposium on Organic Chemistry
http://linked.open...in/vavai/riv/obor
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http://linked.open...UplatneniVysledku
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  • Bureš, Filip
  • Kulhánek, Jiří
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • University of Helsinki
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  • 952-10-2553-0
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  • 25310
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