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Description
| - High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules.
- High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules. (en)
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Title
| - Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
- Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface (en)
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skos:prefLabel
| - Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
- Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface (en)
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skos:notation
| - RIV/00216224:14740/14:00076814!RIV15-MSM-14740___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - I, P(LD13060), P(LD14115)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14740/14:00076814
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Civiš, Svatopluk
- Ferus, Martin
- Kavan, Ladislav
- Zukalová, Markéta
- Šponer, Jiří
- Šponerová, Judit
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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http://localhost/t...ganizacniJednotka
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