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Description
| - The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations.
- The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (en)
- The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (cs)
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Title
| - Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
- Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (en)
- Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (cs)
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skos:prefLabel
| - Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
- Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (en)
- Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (cs)
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skos:notation
| - RIV/00216224:14310/99:00001110!RIV09-MSM-14310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14310/99:00001110
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - crystal structures; copper complexes; diselenoimidodiphosphinato complexes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Marek, Jaromír
- Nečas, Marek
- Novosad, Josef
- Papadimitriou, Christos
- Haiduc, Ionel
- Veltsistas, Panagiotis
- Watanabe, Makoto
- Woollins, Derek J.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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