About: Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A set of CuIXL coordination polymers (X = Cl, Br, I; L = derivatives of pyrazine and bipyridine) with double-stranded staircase structures was analyzed by X-ray crystallography and luminescence spectroscopy to find a relationship between the structure and luminescence properties of the polymers. Our measurements have proved that luminescence emission wavelengths varied between 500–750 nm, after the polymers were irradiated by light with a wavelength of 370 nm. Although each coordination polymer has shown different emission maximum, we observed several interesting trends related to the structure of the compounds. There is a clear correlation between the emission maxima and the halide size and/or Cu–X distance, respectively. On the other hand, the substitution of the ligand L (pyrazine derivatives, 4,40-bipyridine) has no significant contribution to the emission spectra. A set of CuIXL coordination polymers (X = Cl, Br, I; L = derivatives of pyrazine and bipyridine) with double-stranded staircase structures was analyzed by X-ray crystallography and luminescence spectroscopy to find a relationship between the structure and luminescence properties of the polymers. Our measurements have proved that luminescence emission wavelengths varied between 500–750 nm, after the polymers were irradiated by light with a wavelength of 370 nm. Although each coordination polymer has shown different emission maximum, we observed several interesting trends related to the structure of the compounds. There is a clear correlation between the emission maxima and the halide size and/or Cu–X distance, respectively. On the other hand, the substitution of the ligand L (pyrazine derivatives, 4,40-bipyridine) has no significant contribution to the emission spectra. (en)
Title	Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands (en)
skos:prefLabel	Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands (en)
skos:notation	RIV/00216224:14310/11:00049739!RIV12-GA0-14310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA203/08/1111), P(GP203/08/P325)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Nečas, Marek Táborský, Petr Pospíšil, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	210084
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/11:00049739
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	coordination polymers copper luminescence (en)
http://linked.open.../riv/klicoveSlovo	coordination polymers copper luminescence
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[E044AAA8EF1C]
http://linked.open...i/riv/nazevZdroje	New Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Synthesis and properties of inorganic-organic polymeric materials Preparation and study on properties of a new inorganic luminophores containing copper(I)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	35
http://linked.open...iv/tvurceVysledku	Nečas, Marek Pospíšil, Jiří Táborský, Petr Jess, Inke Nather, Christian
issn	1144-0546
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	Luminescence properties of "double-stranded staircase" copper(I) halide coordination polymers with N-containing ligands Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands

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