About: Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	www.asms.org
Description	On-line coupling of column separation techniques with inductively coupled plasma optical emission/mass spectrometry (ICP OES/MS) is routinely used for sensitive, element-selective analysis. Direct linking to ICP usually relies on a nebulizer, which often suffers from reduced separation resolution due to induced liquid flow. Here we report first off-line coupling of capillary electrophoresis (CE) with ICP MS, which is based on eluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations, such as capillary electrophoresis or nano liquid chromatography, in terms of both sensitivity and resolution. Furthermore, the fractions collected on the target can be archived and analyzed using other techniques, e.g. MALDI MS or laser-induced fluorescence. On-line coupling of column separation techniques with inductively coupled plasma optical emission/mass spectrometry (ICP OES/MS) is routinely used for sensitive, element-selective analysis. Direct linking to ICP usually relies on a nebulizer, which often suffers from reduced separation resolution due to induced liquid flow. Here we report first off-line coupling of capillary electrophoresis (CE) with ICP MS, which is based on eluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations, such as capillary electrophoresis or nano liquid chromatography, in terms of both sensitivity and resolution. Furthermore, the fractions collected on the target can be archived and analyzed using other techniques, e.g. MALDI MS or laser-induced fluorescence. (en)
Title	Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation (en)
skos:prefLabel	Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation (en)
skos:notation	RIV/00216224:14310/08:00026062!RIV11-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC06035), Z(MSM0021622411), Z(MSM0021622412), Z(MSM0021622415)
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Vaculovič, Tomáš Preisler, Jan Vyhnánek, Radek Kanický, Viktor Foltynová, Pavla Peš, Ondřej
http://linked.open.../riv/druhVysledku	A(V) - Audiovizuální tvorba se vzdáleným přístupem
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	384426
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/08:00026062
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Electrophoresis Capillary; Elemental Analysis; Laser Ablation; Mass Spectrometry; Inductively Coupled Plasma; Speciation (en)
http://linked.open.../riv/klicoveSlovo	Mass Spectrometry Speciation Electrophoresis Capillary Inductively Coupled Plasma Laser Ablation Elemental Analysis
http://linked.open...i/riv/kodPristupu	V
http://linked.open...ontrolniKodProRIV	[FC6953CE2306]
http://linked.open...i/riv/mistoVydani	Denver, USA
http://linked.open...telVyzkumneZpravy	ASMS
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine.
http://linked.open...UplatneniVysledku	2008
http://linked.open...iv/tvurceVysledku	Kanický, Viktor Preisler, Jan Vaculovič, Tomáš Foltynová, Pavla Peš, Ondřej Vyhnánek, Radek
http://linked.open...rzeVyzkumneZpravy	Proceedings of 56th ASMS Conference
http://linked.open...n/vavai/riv/zamer	Study and application of plasma chemical reactions in non-isothermic low temperature plasma and its interaction with solid surface Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL) Molecular basis of cell and tissue regulations
http://localhost/t...ganizacniJednotka	14310

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