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  • Hydrogen diffusivity in ZnO (0001) single crystal was investigated using electrical resistometry and nuclear reaction analysis (NRA). ZnO crystals were covered with a thin Pd over-layer and electrochemically charged with hydrogen. The net concentration of hydrogen determined by NRA was found to be in a reasonable agreement with the value estimated from the transported charge using the Faraday's law. The hydrogen diffusion coefficient in ZnO was estimated from in-situ electrical resistivity measurements. Moreover, NRA investigations revealed existence of a subsurface layer with very high concentration of hydrogen (up to 40 at.%). Typical surface modification observed on hydrogen loaded crystal by light microscope indicates hydrogen-induced plastic deformation realized by a slip in the c-direction. Open-volume defects introduced by hydrogen-induced plastic deformation trap diffusing hydrogen and cause an enhancement of hydrogen concentration in the deformed subsurface layer.
  • Hydrogen diffusivity in ZnO (0001) single crystal was investigated using electrical resistometry and nuclear reaction analysis (NRA). ZnO crystals were covered with a thin Pd over-layer and electrochemically charged with hydrogen. The net concentration of hydrogen determined by NRA was found to be in a reasonable agreement with the value estimated from the transported charge using the Faraday's law. The hydrogen diffusion coefficient in ZnO was estimated from in-situ electrical resistivity measurements. Moreover, NRA investigations revealed existence of a subsurface layer with very high concentration of hydrogen (up to 40 at.%). Typical surface modification observed on hydrogen loaded crystal by light microscope indicates hydrogen-induced plastic deformation realized by a slip in the c-direction. Open-volume defects introduced by hydrogen-induced plastic deformation trap diffusing hydrogen and cause an enhancement of hydrogen concentration in the deformed subsurface layer. (en)
Title
  • Diffusivity of Hydrogen in ZnO Single Crystal
  • Diffusivity of Hydrogen in ZnO Single Crystal (en)
skos:prefLabel
  • Diffusivity of Hydrogen in ZnO Single Crystal
  • Diffusivity of Hydrogen in ZnO Single Crystal (en)
skos:notation
  • RIV/00216208:11320/12:10127761!RIV13-GA0-11320___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP108/11/0958), S, Z(MSM0021620834)
http://linked.open...iv/cisloPeriodika
  • April, 2012
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
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  • 131298
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11320/12:10127761
http://linked.open...riv/jazykVysledku
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  • nuclear reaction analysis; electrical resistivity; hydrogen; zinc oxide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [06767EB99B55]
http://linked.open...i/riv/nazevZdroje
  • Diffusion and Defect Data. Pt A Defect and Diffusion Forum
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...v/svazekPeriodika
  • 326-328
http://linked.open...iv/tvurceVysledku
  • Lukáč, František
  • Procházka, Ivan
  • Vlček, Marián
  • Čížek, Jakub
  • Becker, Hans-Werner
  • Rogalla, Detlef
  • Traeger, Franziska
http://linked.open...ain/vavai/riv/wos
  • 000309370400079
http://linked.open...n/vavai/riv/zamer
issn
  • 1012-0386
number of pages
http://bibframe.org/vocab/doi
  • 10.4028/www.scientific.net/DDF.326-328.459
http://localhost/t...ganizacniJednotka
  • 11320
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