About: EVOLUTION OF THE CINOVEC (ZINNWALD) GRANITE CUPOLA, CZECH REPUBLIC: COMPOSITION OF FELDSPARS AND MICAS, A CLUE TO THE ORIGIN OF W, Sn MINERALIZATION     Goto   Sponge   Distinct   Permalink

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Description
  • A 1596-m-deep borehole (CS-1) located in the central part of the Cinovec (Zinnwald) granite cupola mineralized in Sn and W intersected zinnwaldite granite (ZG) followed by lithian annite (%22protolithionite%22) granite (PG). These two types of granite are separated by a transition zone (TZ). We studied the chemical composition of major mineral phases (plagioclase, K-feldspar, micas) by EPMA and LA-ICP-MS analyses. The plagioclase composition corresponds to albite (Ab(99.6-91.1)) containing 0.09 to 0.18 wt.% Rb2O. Albite crystallized from the magma. K-feldspar is perthitic and shows an increase in Rb concentration (up to 0.83 wt.% Rb2O) in the apical part of the cupola. The partition coefficient K-D-Rb(Mi-Kfs) is constant throughout the cupola, indicating a systematic re-equilibration of these two minerals with fluid. Lithian annite occurs below -735 m. Its F content decreases with depth and from -940.5 m, OH exceeds F. Magnesium and Ti concentrations show a remarkable positive correlation with depth. The TZ and adjacent area are characterized by strong variations in the chemical composition of micas, reflecting the fluctuation of saturation-oversaturation of residual liquid by a F-rich fluid phase. The Rb concentration in zinnwaldite (up to 2 wt.% Rb2O) strongly increases in the apical part of the cupola owing to a significant transfer of volatiles. The chemical composition of mica evolves gradually from the TZ to the apical zone. The discovery of lithian annite included in quartz at -97 m indicates the formation of zinnwaldite by interaction of lithian annite with F-rich fluid. The octahedral site of lithian annite allows the incorporation of Sn, Nb, Ta and W, replacing Ti. Because of the lithian annite -> zinnwaldite transformation, these elements with higher ionic charges are expelled from the mica structure, transferred to the fluid phase and concentrated in the apical part of the cupola.
  • A 1596-m-deep borehole (CS-1) located in the central part of the Cinovec (Zinnwald) granite cupola mineralized in Sn and W intersected zinnwaldite granite (ZG) followed by lithian annite (%22protolithionite%22) granite (PG). These two types of granite are separated by a transition zone (TZ). We studied the chemical composition of major mineral phases (plagioclase, K-feldspar, micas) by EPMA and LA-ICP-MS analyses. The plagioclase composition corresponds to albite (Ab(99.6-91.1)) containing 0.09 to 0.18 wt.% Rb2O. Albite crystallized from the magma. K-feldspar is perthitic and shows an increase in Rb concentration (up to 0.83 wt.% Rb2O) in the apical part of the cupola. The partition coefficient K-D-Rb(Mi-Kfs) is constant throughout the cupola, indicating a systematic re-equilibration of these two minerals with fluid. Lithian annite occurs below -735 m. Its F content decreases with depth and from -940.5 m, OH exceeds F. Magnesium and Ti concentrations show a remarkable positive correlation with depth. The TZ and adjacent area are characterized by strong variations in the chemical composition of micas, reflecting the fluctuation of saturation-oversaturation of residual liquid by a F-rich fluid phase. The Rb concentration in zinnwaldite (up to 2 wt.% Rb2O) strongly increases in the apical part of the cupola owing to a significant transfer of volatiles. The chemical composition of mica evolves gradually from the TZ to the apical zone. The discovery of lithian annite included in quartz at -97 m indicates the formation of zinnwaldite by interaction of lithian annite with F-rich fluid. The octahedral site of lithian annite allows the incorporation of Sn, Nb, Ta and W, replacing Ti. Because of the lithian annite -> zinnwaldite transformation, these elements with higher ionic charges are expelled from the mica structure, transferred to the fluid phase and concentrated in the apical part of the cupola. (en)
Title
  • EVOLUTION OF THE CINOVEC (ZINNWALD) GRANITE CUPOLA, CZECH REPUBLIC: COMPOSITION OF FELDSPARS AND MICAS, A CLUE TO THE ORIGIN OF W, Sn MINERALIZATION
  • EVOLUTION OF THE CINOVEC (ZINNWALD) GRANITE CUPOLA, CZECH REPUBLIC: COMPOSITION OF FELDSPARS AND MICAS, A CLUE TO THE ORIGIN OF W, Sn MINERALIZATION (en)
skos:prefLabel
  • EVOLUTION OF THE CINOVEC (ZINNWALD) GRANITE CUPOLA, CZECH REPUBLIC: COMPOSITION OF FELDSPARS AND MICAS, A CLUE TO THE ORIGIN OF W, Sn MINERALIZATION
  • EVOLUTION OF THE CINOVEC (ZINNWALD) GRANITE CUPOLA, CZECH REPUBLIC: COMPOSITION OF FELDSPARS AND MICAS, A CLUE TO THE ORIGIN OF W, Sn MINERALIZATION (en)
skos:notation
  • RIV/00216208:11310/12:10133917!RIV13-MSM-11310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021620855)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 135305
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/12:10133917
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Czech Republic; Cinovec (Zinnwald); metallogenic model; F-rich fluid; lithian annite -> zinnwaldite transformation; Sn, Nb, Ta and W concentrations in micas; lithian annite; zinnwaldite; granite cupola (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CA - Kanada
http://linked.open...ontrolniKodProRIV
  • [BC2596C25401]
http://linked.open...i/riv/nazevZdroje
  • Canadian Mineralogist
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 50
http://linked.open...iv/tvurceVysledku
  • Strnad, Ladislav
  • Johan, Vera
  • Johan, Zdenek
http://linked.open...ain/vavai/riv/wos
  • 000314174400021
http://linked.open...n/vavai/riv/zamer
issn
  • 0008-4476
number of pages
http://bibframe.org/vocab/doi
  • 10.3749/canmin.50.4.1131
http://localhost/t...ganizacniJednotka
  • 11310
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