About: [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate)     Goto   Sponge   Distinct   Permalink

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Description
  • The centrosymmetric dinuclear cadmium title complex was obtained by the reaction of N,N0-bis(2-aminoethyl)ethane-1,2-diamine (trien) with Cd(NO3)2. 4H2O and sodium perchlorate in methanol. The CdII cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octahedral coordination geometry. The bridging ligand shares another two N atoms with a neighboring symmetry-equivalent CdII cation. The structure displays C-H...O and N-H...O hydrogen bonding. The perchlorate anion is disordered.
  • The centrosymmetric dinuclear cadmium title complex was obtained by the reaction of N,N0-bis(2-aminoethyl)ethane-1,2-diamine (trien) with Cd(NO3)2. 4H2O and sodium perchlorate in methanol. The CdII cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octahedral coordination geometry. The bridging ligand shares another two N atoms with a neighboring symmetry-equivalent CdII cation. The structure displays C-H...O and N-H...O hydrogen bonding. The perchlorate anion is disordered. (en)
Title
  • [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate)
  • [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate) (en)
skos:prefLabel
  • [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate)
  • [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate) (en)
skos:notation
  • RIV/68378271:_____/12:00384806!RIV13-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika
  • Part 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 183164
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/12:00384806
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • x-ray structure; cadmium; perchlorate; disorder; weak interactions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [7434C319FC54]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 68
http://linked.open...iv/tvurceVysledku
  • Dušek, Michal
  • Eigner, Václav
  • Abbasityula, Y.
  • Goudarziafshar, H.
http://linked.open...n/vavai/riv/zamer
issn
  • 1600-5368
number of pages
http://bibframe.org/vocab/doi
  • 10.1107/S1600536812033880
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