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Description
| - Navržený korelační vztah umožňuje spolehlivou předpověď reakčních rychlosti jako funkci teploty a stupně rozkladu. (cs)
- The decomposition rate of aluminum chloride hexahydrate (AlCl3.6H2O) was measured as weight loss at ambient pressure and elevated temperatures up to 270oC. Such incomplete, thermal decomposition produces a porous and reactive basic aluminum chloride [Al2O3.2HCl.2H2O or Al2(OH)4Cl2.H2O] which dissolves in water to give poly(aluminum chloride) used as an efficient flocculation agent. A slowly rising-temperature method and very small sample masses, which minimize heat and mass transfer intrusions, were employed to determine intrinsic reaction rates. A fractional order kinetic equation of Arrhenius type was proposed for the decomposition and tested also against the results amassed by experiment in a constant temperature mode. This correlation allows the estimation of the reaction rate as a function of temperature and the extent of decomposition. It can readily be employed in modeling and simulation of the decomposition process.
- The decomposition rate of aluminum chloride hexahydrate (AlCl3.6H2O) was measured as weight loss at ambient pressure and elevated temperatures up to 270oC. Such incomplete, thermal decomposition produces a porous and reactive basic aluminum chloride [Al2O3.2HCl.2H2O or Al2(OH)4Cl2.H2O] which dissolves in water to give poly(aluminum chloride) used as an efficient flocculation agent. A slowly rising-temperature method and very small sample masses, which minimize heat and mass transfer intrusions, were employed to determine intrinsic reaction rates. A fractional order kinetic equation of Arrhenius type was proposed for the decomposition and tested also against the results amassed by experiment in a constant temperature mode. This correlation allows the estimation of the reaction rate as a function of temperature and the extent of decomposition. It can readily be employed in modeling and simulation of the decomposition process. (en)
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Title
| - Thermal Decomposition of Aluminium Chloride Hexahydrate
- Thermal Decomposition of Aluminium Chloride Hexahydrate (en)
- Tepelný rozklad AlCl3.6H2O (cs)
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skos:prefLabel
| - Thermal Decomposition of Aluminium Chloride Hexahydrate
- Thermal Decomposition of Aluminium Chloride Hexahydrate (en)
- Tepelný rozklad AlCl3.6H2O (cs)
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skos:notation
| - RIV/67985858:_____/05:00028622!RIV06-AV0-67985858
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/02/0002), Z(AV0Z40720504)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/67985858:_____/05:00028622
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - aluminum chloride hexahydrate; thermal decomposition; reaction kinetics (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Industrial and Engineering Chemistry Research
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Šolcová, Olga
- Hartman, Miloslav
- Trnka, Otakar
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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