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rdf:type
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Description
| - The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set.
- The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set. (en)
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Title
| - Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands
- Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands (en)
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skos:prefLabel
| - Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands
- Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands (en)
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skos:notation
| - RIV/61989592:15310/11:10222340!RIV12-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(ED2.1.00/03.0058), Z(MSM6198959218)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/11:10222340
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Nickel(II) complexes, Hexamethyleneimine, Dithiocarbamate, X-ray structure (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Trávníček, Zdeněk
- Štarha, Pavel
- Pastorek, Richard
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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