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rdf:type
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Description
| - Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an
- Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an (en)
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Title
| - Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes
- Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes (en)
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skos:prefLabel
| - Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes
- Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes (en)
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skos:notation
| - RIV/61989592:15310/07:00005816!RIV10-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(IAA400310613), S, Z(AV0Z40310501), Z(MSM6198959216)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/07:00005816
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Boron cluster compound; CE; Chiral separation; Cyclodextrin; Mixed solvent (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Horáková, Hana
- Vespalec, Radim
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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