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rdf:type
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Description
| - Mixed-ligand Ni(II) complexes involving thioglycolate(2-) (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H2O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H2O (2), [Ni(phen)(tdga)(H2O)].H2O (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine, en = ethylenediamine, phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-VIS spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B) and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H2O (1). A binuclear structure of c
- Mixed-ligand Ni(II) complexes involving thioglycolate(2-) (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H2O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H2O (2), [Ni(phen)(tdga)(H2O)].H2O (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine, en = ethylenediamine, phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-VIS spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B) and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H2O (1). A binuclear structure of c (en)
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Title
| - Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)
- Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid) (en)
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skos:prefLabel
| - Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)
- Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid) (en)
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skos:notation
| - RIV/61989592:15310/04:00009894!RIV10-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/02/0436), Z(MSM 143100008), Z(MSM 153100007)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/04:00009894
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - nickel(II); thiodiglycolic acid complexes; X-ray complexes; magnetic properties (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Marek, Jaromír
- Trávníček, Zdeněk
- Kopel, Pavel
- Mroziński, Jerzy
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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