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Description
| - The crystal and molecular structure of the title complex compound (dimeen = N,N-dimethylethylenediamine, ox = oxalate) has been solved by heavy atom methods and basic physico-chemical measurements have been made. It was found that the structure contains two non-equivalent copper atoms in the slightly distorted square-planar for Cu(2) and square-pyramidal for Cu(1) coordination with deviations of atom positions from ideal Cu(1)N(1)N(2)O(3)O(4) plane smaller then 0.28 A.The results of magnetochemical measurements (#eff = 1.82 BM/294 K) correspond with assumption of copper in the oxidation state II. The value of molar conductivity in water (c = 10-3 mol/l, lM = 307 Scm2mol-1) confirms the 1:2 electrolyte with ClO4- group out from the coordination sphere of both central atoms; the characteristic absorption for this group at 1068 cm-1 and 620 cm-1 were also found in the IR-spectrum.
- The crystal and molecular structure of the title complex compound (dimeen = N,N-dimethylethylenediamine, ox = oxalate) has been solved by heavy atom methods and basic physico-chemical measurements have been made. It was found that the structure contains two non-equivalent copper atoms in the slightly distorted square-planar for Cu(2) and square-pyramidal for Cu(1) coordination with deviations of atom positions from ideal Cu(1)N(1)N(2)O(3)O(4) plane smaller then 0.28 A.The results of magnetochemical measurements (#eff = 1.82 BM/294 K) correspond with assumption of copper in the oxidation state II. The value of molar conductivity in water (c = 10-3 mol/l, lM = 307 Scm2mol-1) confirms the 1:2 electrolyte with ClO4- group out from the coordination sphere of both central atoms; the characteristic absorption for this group at 1068 cm-1 and 620 cm-1 were also found in the IR-spectrum. (en)
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Title
| - X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2.
- X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2. (en)
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skos:prefLabel
| - X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2.
- X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2. (en)
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skos:notation
| - RIV/61989592:15310/01:00001528!RIV/2003/MSM/153103/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/01:00001528
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Materials Structure in Chemistry, Biology, Physics and Technology
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Smékal, Zdeněk
- Kameníček, Jiří
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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