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  • The photoactive quartz sand/TiO2 composites were prepared by thermal hydrolysis of the suspension obtained by addition of quartz sand to a titanyl sulfate solution. The required amount of TiO2 in the prepared composites (i.e 9, 22 and 45 wt. %, respectively) was achieved using a variable titanyl sulfate/quartz ratio. As reference materials, pure TiO2 was prepared using the thermal hydrolysis of the titanyl sulfate solution under the same condition as used during the preparation of composite quartz/TiO2. The composite samples, dried at 105°C and calcined at temperatures of 500-900°C, were investigated using X-ray fluorescence spectroscopy, X-ray powder diffraction analysis, transmission electron microscopy, and Fourier transform infrared spectroscopy. Structural ordering of TiO2 particles on the quartz surface was studied using atomistic simulations in a Material Studio modeling environment. Photodegradation activity of the composites was evaluated by the discoloration of Acid Orange 7 aqueous solution. The composite containing 22 wt.% of TiO2 and calcined at 800°C exhibits the highest photoactivity. Higher and lower amounts of TiO2 led to worse results. The quartz/TiO2 composite is a promising material able to replace pure TiO2 in a wide range of building materials.
  • The photoactive quartz sand/TiO2 composites were prepared by thermal hydrolysis of the suspension obtained by addition of quartz sand to a titanyl sulfate solution. The required amount of TiO2 in the prepared composites (i.e 9, 22 and 45 wt. %, respectively) was achieved using a variable titanyl sulfate/quartz ratio. As reference materials, pure TiO2 was prepared using the thermal hydrolysis of the titanyl sulfate solution under the same condition as used during the preparation of composite quartz/TiO2. The composite samples, dried at 105°C and calcined at temperatures of 500-900°C, were investigated using X-ray fluorescence spectroscopy, X-ray powder diffraction analysis, transmission electron microscopy, and Fourier transform infrared spectroscopy. Structural ordering of TiO2 particles on the quartz surface was studied using atomistic simulations in a Material Studio modeling environment. Photodegradation activity of the composites was evaluated by the discoloration of Acid Orange 7 aqueous solution. The composite containing 22 wt.% of TiO2 and calcined at 800°C exhibits the highest photoactivity. Higher and lower amounts of TiO2 led to worse results. The quartz/TiO2 composite is a promising material able to replace pure TiO2 in a wide range of building materials. (en)
Title
  • A low-cost photoactive composite quartz sand/TiO2
  • A low-cost photoactive composite quartz sand/TiO2 (en)
skos:prefLabel
  • A low-cost photoactive composite quartz sand/TiO2
  • A low-cost photoactive composite quartz sand/TiO2 (en)
skos:notation
  • RIV/61989100:27640/13:86084575!RIV14-MSM-27640___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(ED1.1.00/02.0070), S
http://linked.open...iv/cisloPeriodika
  • 25.3.2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 58698
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27640/13:86084575
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • photoactivity; nanocomposite; TiO2; quartz sand (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • BE - Belgické království
http://linked.open...ontrolniKodProRIV
  • [C16E54608BD0]
http://linked.open...i/riv/nazevZdroje
  • Chemical engineering journal
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 222
http://linked.open...iv/tvurceVysledku
  • Matějka, Vlastimil
  • Čapková, Pavla
  • Neuwirthová, Lucie
  • Kukutschová, Jana
  • Mamulová Kutláková, Kateřina
  • Tokarský, Jonáš
  • Vontorová, Jiřina
http://linked.open...ain/vavai/riv/wos
  • 000319528900055
issn
  • 1385-8947
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.cej.2013.02.056
http://localhost/t...ganizacniJednotka
  • 27640
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