About: Effect of clay on structure of epoxy/PCL nanocomposite: in situ optical microscopy study     Goto   Sponge   Distinct   Permalink

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  • The effect of clay on reaction induced phase separation (RIPS) mechanism and resulting morphology of diglycidyl ether of bisphenol-A based epoxy containing poly(ε-caprolactone)(PCL) was investigated by optical microscopy. At PCL concentration lower than 10%, the presence of the clay leads to refinement of PCL inclusions, while at 15% and 20% the clay causes the phase inversion of structure consisting of PCL rich matrix with rough epoxy globules to the fine PCL inclusions in epoxy matrix. At 30% PCL content, the influence of clay is analogical but leads to the transformation into co-continous structure only. These changes in morphology seem to be a consequence of the change in dynamic asymmetry of the system, caused by affecting of the epoxy parameters by clay.
  • The effect of clay on reaction induced phase separation (RIPS) mechanism and resulting morphology of diglycidyl ether of bisphenol-A based epoxy containing poly(ε-caprolactone)(PCL) was investigated by optical microscopy. At PCL concentration lower than 10%, the presence of the clay leads to refinement of PCL inclusions, while at 15% and 20% the clay causes the phase inversion of structure consisting of PCL rich matrix with rough epoxy globules to the fine PCL inclusions in epoxy matrix. At 30% PCL content, the influence of clay is analogical but leads to the transformation into co-continous structure only. These changes in morphology seem to be a consequence of the change in dynamic asymmetry of the system, caused by affecting of the epoxy parameters by clay. (en)
Title
  • Effect of clay on structure of epoxy/PCL nanocomposite: in situ optical microscopy study
  • Effect of clay on structure of epoxy/PCL nanocomposite: in situ optical microscopy study (en)
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  • Effect of clay on structure of epoxy/PCL nanocomposite: in situ optical microscopy study
  • Effect of clay on structure of epoxy/PCL nanocomposite: in situ optical microscopy study (en)
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  • RIV/61389013:_____/12:00379708!RIV13-AV0-61389013
http://linked.open...avai/riv/aktivita
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  • I, P(IAA200500904), Z(AV0Z40500505)
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  • 132971
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  • RIV/61389013:_____/12:00379708
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  • epoxy nanocomposites; optical microscopy; microstructure (en)
http://linked.open.../riv/klicoveSlovo
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  • [1130893742AE]
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  • Ischia
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  • Melville
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  • 6th international conference on times of polymers (TOP) and composites - AIP Conference Proceedings
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  • Kelnar, Ivan
  • Rotrekl, Jakub
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  • 000306738500078
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number of pages
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  • 10.1063/1.4738457
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  • American Institute of Physics (AIP)
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  • 978-0-7354-1062-6
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