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rdf:type
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Description
| - Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4.
- Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4. (en)
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Title
| - Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
- Cyclopentadienyl ruthenium comlexes with tricarbolide ligands (en)
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skos:prefLabel
| - Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
- Cyclopentadienyl ruthenium comlexes with tricarbolide ligands (en)
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skos:notation
| - RIV/61388980:_____/10:00354532!RIV11-MSM-61388980
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(LC523), Z(AV0Z40320502)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/10:00354532
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - boron; metallacarborane; ruthenium; tricarbollide (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Collection of Czechoslovak Chemical Communications
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Holub, Josef
- Kudinov, A. R.
- Glukhov, I. V.
- Perekalin, D. S.
- Trifonova, E. A.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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