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rdf:type
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Description
| - Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom.
- Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom. (en)
- Popsána je příprava a genese dvou nových sloučenin v 19-vrcholové iridaboranové řadě. (cs)
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Title
| - Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM...
- Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM... (en)
- Makropolyedrická borová chemie. Dvouelektronové variace intraklastrové vazebné intimity indukované ligandem.. Struktury 19-vrcholového ... a podobného karbenového komplexu (cs)
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skos:prefLabel
| - Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM...
- Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM... (en)
- Makropolyedrická borová chemie. Dvouelektronové variace intraklastrové vazebné intimity indukované ligandem.. Struktury 19-vrcholového ... a podobného karbenového komplexu (cs)
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skos:notation
| - RIV/61388980:_____/04:00108166!RIV/2005/AV0/A50005/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(IAA4032701), Z(AV0Z4032918)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/04:00108166
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - carboranes; 19-vertex; boranes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Jelínek, Tomáš
- Kennedy, J. D.
- Štíbr, Bohumil
- Thornton-Pett, M.
- Perera, S. D.
- Shea, S. L.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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